Using pyridine amidoximes in 3d-metal cluster chemistry: A novel ferromagnetic Ni12 complex from the use of pyridine-2-amidoxime

Constantina Papatriantafyllopoulou; Leigh F. Jones; Tuyen D. Nguyen; Nuria Matamoros-Salvador; Luís Cunha-Silva; Filipe A. Almeida Paz; João Rocha; Marco Evangelisti; Euan K. Brechin; Spyros P. Perlepes

doi:10.1039/b802927j

Using pyridine amidoximes in 3d-metal cluster chemistry: A novel ferromagnetic Ni₁₂ complex from the use of pyridine-2-amidoxime

Constantina Papatriantafyllopoulou, Leigh F. Jones, Tuyen D. Nguyen, Nuria Matamoros-Salvador, Luís Cunha-Silva, Filipe A. Almeida Paz, João Rocha, Marco Evangelisti, Euan K. Brechin, Spyros P. Perlepes

Research output: Contribution to a Journal (Peer & Non Peer) › Article › peer-review

49 Citations (Scopus)

Abstract

The use of pyridine-2-amidoxime in reaction with NiCl₂• 6H₂O in the presence of NaOMe has led to a cationic Ni ^II₁₂ cluster with novel structural features; each cluster molecule is a ferromagnet with a spin ground state of S = 6 arising from ferromagnetic exchange between the six octahedral Ni^II ions, but with intercationic interactions also affecting the magnetic properties.

Original language	English
Pages (from-to)	3153-3155
Number of pages	3
Journal	Dalton Transactions
Issue number	24
DOIs	https://doi.org/10.1039/b802927j
Publication status	Published - 2008
Externally published	Yes

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Papatriantafyllopoulou, C., Jones, L. F., Nguyen, T. D., Matamoros-Salvador, N., Cunha-Silva, L., Almeida Paz, F. A., Rocha, J., Evangelisti, M., Brechin, E. K., & Perlepes, S. P. (2008). Using pyridine amidoximes in 3d-metal cluster chemistry: A novel ferromagnetic Ni₁₂ complex from the use of pyridine-2-amidoxime. Dalton Transactions, (24), 3153-3155. https://doi.org/10.1039/b802927j

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title = "Using pyridine amidoximes in 3d-metal cluster chemistry: A novel ferromagnetic Ni12 complex from the use of pyridine-2-amidoxime",

abstract = "The use of pyridine-2-amidoxime in reaction with NiCl2• 6H2O in the presence of NaOMe has led to a cationic Ni II12 cluster with novel structural features; each cluster molecule is a ferromagnet with a spin ground state of S = 6 arising from ferromagnetic exchange between the six octahedral NiII ions, but with intercationic interactions also affecting the magnetic properties.",

author = "Constantina Papatriantafyllopoulou and Jones, \{Leigh F.\} and Nguyen, \{Tuyen D.\} and Nuria Matamoros-Salvador and Lu{\'i}s Cunha-Silva and \{Almeida Paz\}, \{Filipe A.\} and Jo{\~a}o Rocha and Marco Evangelisti and Brechin, \{Euan K.\} and Perlepes, \{Spyros P.\}",

year = "2008",

doi = "10.1039/b802927j",

language = "English",

pages = "3153--3155",

journal = "Dalton Transactions",

issn = "1477-9226",

publisher = "Royal Society of Chemistry",

number = "24",

}

Papatriantafyllopoulou, C, Jones, LF, Nguyen, TD, Matamoros-Salvador, N, Cunha-Silva, L, Almeida Paz, FA, Rocha, J, Evangelisti, M, Brechin, EK & Perlepes, SP 2008, 'Using pyridine amidoximes in 3d-metal cluster chemistry: A novel ferromagnetic Ni₁₂ complex from the use of pyridine-2-amidoxime', Dalton Transactions, no. 24, pp. 3153-3155. https://doi.org/10.1039/b802927j

TY - JOUR

T1 - Using pyridine amidoximes in 3d-metal cluster chemistry

T2 - A novel ferromagnetic Ni12 complex from the use of pyridine-2-amidoxime

AU - Papatriantafyllopoulou, Constantina

AU - Jones, Leigh F.

AU - Nguyen, Tuyen D.

AU - Matamoros-Salvador, Nuria

AU - Cunha-Silva, Luís

AU - Almeida Paz, Filipe A.

AU - Rocha, João

AU - Evangelisti, Marco

AU - Brechin, Euan K.

AU - Perlepes, Spyros P.

PY - 2008

Y1 - 2008

N2 - The use of pyridine-2-amidoxime in reaction with NiCl2• 6H2O in the presence of NaOMe has led to a cationic Ni II12 cluster with novel structural features; each cluster molecule is a ferromagnet with a spin ground state of S = 6 arising from ferromagnetic exchange between the six octahedral NiII ions, but with intercationic interactions also affecting the magnetic properties.

AB - The use of pyridine-2-amidoxime in reaction with NiCl2• 6H2O in the presence of NaOMe has led to a cationic Ni II12 cluster with novel structural features; each cluster molecule is a ferromagnet with a spin ground state of S = 6 arising from ferromagnetic exchange between the six octahedral NiII ions, but with intercationic interactions also affecting the magnetic properties.

UR - https://www.scopus.com/pages/publications/45149105832

U2 - 10.1039/b802927j

DO - 10.1039/b802927j

M3 - Article

SN - 1477-9226

SP - 3153

EP - 3155

JO - Dalton Transactions

JF - Dalton Transactions

IS - 24

ER -

Using pyridine amidoximes in 3d-metal cluster chemistry: A novel ferromagnetic Ni₁₂ complex from the use of pyridine-2-amidoxime

Abstract

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