Transition metal Schiff-base complexes as ligands in tin chemistry. IV. Reactions of triphenyltin chloride with divalent metal salicylaldimine complexes and the molecular structures of...

N. Clarke; D. Cunningham; T. Higgins; P. McArdle; J. McGinley; M. O'Gara

doi:10.1016/0022-328X(94)80075-8

Transition metal Schiff-base complexes as ligands in tin chemistry. IV. Reactions of triphenyltin chloride with divalent metal salicylaldimine complexes and the molecular structures of...

N. Clarke
, D. Cunningham
, T. Higgins
, P. McArdle
, J. McGinley
, M. O'Gara

University of Galway

Research output: Contribution to a Journal (Peer & Non Peer) › Article › peer-review

27 Citations (Scopus)

Abstract

Title full: Transition metal Schiff-base complexes as ligands in tin chemistry. IV. Reactions of triphenyltin chloride with divalent metal salicylaldimine complexes and the molecular structures of [SnPh₃Cl · H₂O][Ni(3-MeOsal1,3pn) · H₂O] (1:1) and [SnPh₃Cl · H₂O]Ni(3-MeOsal1,3pren) (1:1) [H₂3-MeOsal1,3pn N,N′-bis(3-methoxysalicylidene)propane-1,3-diamine]. Unlike diorganotin(IV) dihalides, triphenyl- and tribenzyl-tin chlorides do not react with Schiff-base complexes M(SB) (M Cu^II, Ni^II and Zn^II; SB N,N′-ethylenebis-salicylideneaminato and related salicylaldimine ligands). Triphenyltin chloride does however form 1:1 addition complexes with 3,3′-methoxy substituted salicylaldimines of Ni^II and Cu^II, but only in the presence of water. Each of these complexes contains the aquo adduct SnPh₃Cl · H₂O, with the donor water molecule engaged in hydrogen bonding interactions with the four oxygen atoms of the divalent metal salicyaldimine. These structural features were confirmed crystallographically for (SnPh₃Cl · H₂O)Ni(3-MeOsal1,3pn) (1:1) [H₂3-MeOsal1,3pn N,N′-bis(3-methoxysalicylidene)propane-1,3-diamine]. In the case of [SnPh₃Cl · H₂O][Ni(3-MeOsal1,3pn) · H₂O] (1:1) both the water molecule coordinated to nickel and the water molecule coordinated to tin engage in hydrogen bonding interactions with the Schiff-base oxygen atoms, thereby creating centrosymmetric hydrogen-bonded dimers.

Original language	English
Pages (from-to)	33-40
Number of pages	8
Journal	Journal of Organometallic Chemistry
Volume	469
Issue number	1
DOIs	https://doi.org/10.1016/0022-328X(94)80075-8
Publication status	Published - 19 Apr 1994
Externally published	Yes

Keywords

Mössbauer spectroscopy
Tin

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10.1016/0022-328X(94)80075-8

Cite this

Clarke, N., Cunningham, D., Higgins, T., McArdle, P., McGinley, J., & O'Gara, M. (1994). Transition metal Schiff-base complexes as ligands in tin chemistry. IV. Reactions of triphenyltin chloride with divalent metal salicylaldimine complexes and the molecular structures of... Journal of Organometallic Chemistry, 469(1), 33-40. https://doi.org/10.1016/0022-328X(94)80075-8

@article{11918e7dd16642969d290d71d10747a8,

title = "Transition metal Schiff-base complexes as ligands in tin chemistry. IV. Reactions of triphenyltin chloride with divalent metal salicylaldimine complexes and the molecular structures of...",

abstract = "Title full: Transition metal Schiff-base complexes as ligands in tin chemistry. IV. Reactions of triphenyltin chloride with divalent metal salicylaldimine complexes and the molecular structures of [SnPh3Cl · H2O][Ni(3-MeOsal1,3pn) · H2O] (1:1) and [SnPh3Cl · H2O]Ni(3-MeOsal1,3pren) (1:1) [H23-MeOsal1,3pn N,N′-bis(3-methoxysalicylidene)propane-1,3-diamine]. Unlike diorganotin(IV) dihalides, triphenyl- and tribenzyl-tin chlorides do not react with Schiff-base complexes M(SB) (M CuII, NiII and ZnII; SB N,N′-ethylenebis-salicylideneaminato and related salicylaldimine ligands). Triphenyltin chloride does however form 1:1 addition complexes with 3,3′-methoxy substituted salicylaldimines of NiII and CuII, but only in the presence of water. Each of these complexes contains the aquo adduct SnPh3Cl · H2O, with the donor water molecule engaged in hydrogen bonding interactions with the four oxygen atoms of the divalent metal salicyaldimine. These structural features were confirmed crystallographically for (SnPh3Cl · H2O)Ni(3-MeOsal1,3pn) (1:1) [H23-MeOsal1,3pn N,N′-bis(3-methoxysalicylidene)propane-1,3-diamine]. In the case of [SnPh3Cl · H2O][Ni(3-MeOsal1,3pn) · H2O] (1:1) both the water molecule coordinated to nickel and the water molecule coordinated to tin engage in hydrogen bonding interactions with the Schiff-base oxygen atoms, thereby creating centrosymmetric hydrogen-bonded dimers.",

keywords = "M{\"o}ssbauer spectroscopy, Tin",

author = "N. Clarke and D. Cunningham and T. Higgins and P. McArdle and J. McGinley and M. O'Gara",

year = "1994",

month = apr,

day = "19",

doi = "10.1016/0022-328X(94)80075-8",

language = "English",

volume = "469",

pages = "33--40",

journal = "Journal of Organometallic Chemistry",

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}

Clarke, N, Cunningham, D, Higgins, T, McArdle, P, McGinley, J & O'Gara, M 1994, 'Transition metal Schiff-base complexes as ligands in tin chemistry. IV. Reactions of triphenyltin chloride with divalent metal salicylaldimine complexes and the molecular structures of...', Journal of Organometallic Chemistry, vol. 469, no. 1, pp. 33-40. https://doi.org/10.1016/0022-328X(94)80075-8

Transition metal Schiff-base complexes as ligands in tin chemistry. IV. Reactions of triphenyltin chloride with divalent metal salicylaldimine complexes and the molecular structures of... / Clarke, N.; Cunningham, D.; Higgins, T. et al.
In: Journal of Organometallic Chemistry, Vol. 469, No. 1, 19.04.1994, p. 33-40.

Research output: Contribution to a Journal (Peer & Non Peer) › Article › peer-review

TY - JOUR

T1 - Transition metal Schiff-base complexes as ligands in tin chemistry. IV. Reactions of triphenyltin chloride with divalent metal salicylaldimine complexes and the molecular structures of...

AU - Clarke, N.

AU - Cunningham, D.

AU - Higgins, T.

AU - McArdle, P.

AU - McGinley, J.

AU - O'Gara, M.

PY - 1994/4/19

Y1 - 1994/4/19

N2 - Title full: Transition metal Schiff-base complexes as ligands in tin chemistry. IV. Reactions of triphenyltin chloride with divalent metal salicylaldimine complexes and the molecular structures of [SnPh3Cl · H2O][Ni(3-MeOsal1,3pn) · H2O] (1:1) and [SnPh3Cl · H2O]Ni(3-MeOsal1,3pren) (1:1) [H23-MeOsal1,3pn N,N′-bis(3-methoxysalicylidene)propane-1,3-diamine]. Unlike diorganotin(IV) dihalides, triphenyl- and tribenzyl-tin chlorides do not react with Schiff-base complexes M(SB) (M CuII, NiII and ZnII; SB N,N′-ethylenebis-salicylideneaminato and related salicylaldimine ligands). Triphenyltin chloride does however form 1:1 addition complexes with 3,3′-methoxy substituted salicylaldimines of NiII and CuII, but only in the presence of water. Each of these complexes contains the aquo adduct SnPh3Cl · H2O, with the donor water molecule engaged in hydrogen bonding interactions with the four oxygen atoms of the divalent metal salicyaldimine. These structural features were confirmed crystallographically for (SnPh3Cl · H2O)Ni(3-MeOsal1,3pn) (1:1) [H23-MeOsal1,3pn N,N′-bis(3-methoxysalicylidene)propane-1,3-diamine]. In the case of [SnPh3Cl · H2O][Ni(3-MeOsal1,3pn) · H2O] (1:1) both the water molecule coordinated to nickel and the water molecule coordinated to tin engage in hydrogen bonding interactions with the Schiff-base oxygen atoms, thereby creating centrosymmetric hydrogen-bonded dimers.

AB - Title full: Transition metal Schiff-base complexes as ligands in tin chemistry. IV. Reactions of triphenyltin chloride with divalent metal salicylaldimine complexes and the molecular structures of [SnPh3Cl · H2O][Ni(3-MeOsal1,3pn) · H2O] (1:1) and [SnPh3Cl · H2O]Ni(3-MeOsal1,3pren) (1:1) [H23-MeOsal1,3pn N,N′-bis(3-methoxysalicylidene)propane-1,3-diamine]. Unlike diorganotin(IV) dihalides, triphenyl- and tribenzyl-tin chlorides do not react with Schiff-base complexes M(SB) (M CuII, NiII and ZnII; SB N,N′-ethylenebis-salicylideneaminato and related salicylaldimine ligands). Triphenyltin chloride does however form 1:1 addition complexes with 3,3′-methoxy substituted salicylaldimines of NiII and CuII, but only in the presence of water. Each of these complexes contains the aquo adduct SnPh3Cl · H2O, with the donor water molecule engaged in hydrogen bonding interactions with the four oxygen atoms of the divalent metal salicyaldimine. These structural features were confirmed crystallographically for (SnPh3Cl · H2O)Ni(3-MeOsal1,3pn) (1:1) [H23-MeOsal1,3pn N,N′-bis(3-methoxysalicylidene)propane-1,3-diamine]. In the case of [SnPh3Cl · H2O][Ni(3-MeOsal1,3pn) · H2O] (1:1) both the water molecule coordinated to nickel and the water molecule coordinated to tin engage in hydrogen bonding interactions with the Schiff-base oxygen atoms, thereby creating centrosymmetric hydrogen-bonded dimers.

KW - Mössbauer spectroscopy

KW - Tin

UR - https://www.scopus.com/pages/publications/0002583521

U2 - 10.1016/0022-328X(94)80075-8

DO - 10.1016/0022-328X(94)80075-8

M3 - Article

SN - 0022-328X

VL - 469

SP - 33

EP - 40

JO - Journal of Organometallic Chemistry

JF - Journal of Organometallic Chemistry

IS - 1

ER -

Transition metal Schiff-base complexes as ligands in tin chemistry. IV. Reactions of triphenyltin chloride with divalent metal salicylaldimine complexes and the molecular structures of...

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