The structure of bis(dimethyldithioarsinato)gallium(III) sulfide [(Me 2AsS2)2Ga]2S·0.75H 2O: A hydrolysis product of (Me2AsS2) 3Ga that contains a bridging sulfide and both pendant and bridging dimethyldithioarsinato ligands

Constantina Papatriantafyllopoulou; Vassilios Nastopoulos; Panayiotis V. Ioannou

doi:10.1002/zaac.201400076

The structure of bis(dimethyldithioarsinato)gallium(III) sulfide [(Me ₂AsS₂)₂Ga]₂S·0.75H ₂O: A hydrolysis product of (Me₂AsS₂) ₃Ga that contains a bridging sulfide and both pendant and bridging dimethyldithioarsinato ligands

Constantina Papatriantafyllopoulou
, Vassilios Nastopoulos
, Panayiotis V. Ioannou

University of Cyprus
University of Patras

Research output: Contribution to a Journal (Peer & Non Peer) › Article › peer-review

1 Citation (Scopus)

Abstract

The complex (Me₂AsS₂)₃Ga (1) attracted water molecules that slowly and completely hydrolyzed it. The product was the dinuclear gallium compound (Me₂AsS₂)₂Ga-S- Ga(S₂AsMe₂)₂ (2) as 2·0.75H ₂O, which was structurally characterized with X-ray crystallography (P2₁2₁2₁, R₁ = 0.0321, wR ₂ = 0.0622). Compound 2 shows an approximate non-crystallographic twofold axis. The packing in the crystalline state is dictated by the mediation of crystallization water molecules, which connect the complex units through strong O-H⋯S and weak C-H⋯O hydrogen bonds into infinite zigzag chains.

Original language	English
Pages (from-to)	1654-1657
Number of pages	4
Journal	Zeitschrift fur Anorganische und Allgemeine Chemie
Volume	640
Issue number	8-9
DOIs	https://doi.org/10.1002/zaac.201400076
Publication status	Published - Jul 2014
Externally published	Yes

Keywords

Dimethyldithioarsinato ligand
Gallium
X-ray crystallography

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Papatriantafyllopoulou, C., Nastopoulos, V., & Ioannou, P. V. (2014). The structure of bis(dimethyldithioarsinato)gallium(III) sulfide [(Me ₂AsS₂)₂Ga]₂S·0.75H ₂O: A hydrolysis product of (Me₂AsS₂) ₃Ga that contains a bridging sulfide and both pendant and bridging dimethyldithioarsinato ligands. Zeitschrift fur Anorganische und Allgemeine Chemie, 640(8-9), 1654-1657. https://doi.org/10.1002/zaac.201400076

Papatriantafyllopoulou, Constantina ; Nastopoulos, Vassilios ; Ioannou, Panayiotis V. / The structure of bis(dimethyldithioarsinato)gallium(III) sulfide [(Me ₂AsS₂)₂Ga]₂S·0.75H ₂O : A hydrolysis product of (Me₂AsS₂) ₃Ga that contains a bridging sulfide and both pendant and bridging dimethyldithioarsinato ligands. In: Zeitschrift fur Anorganische und Allgemeine Chemie. 2014 ; Vol. 640, No. 8-9. pp. 1654-1657.

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title = "The structure of bis(dimethyldithioarsinato)gallium(III) sulfide [(Me 2AsS2)2Ga]2S·0.75H 2O: A hydrolysis product of (Me2AsS2) 3Ga that contains a bridging sulfide and both pendant and bridging dimethyldithioarsinato ligands",

abstract = "The complex (Me2AsS2)3Ga (1) attracted water molecules that slowly and completely hydrolyzed it. The product was the dinuclear gallium compound (Me2AsS2)2Ga-S- Ga(S2AsMe2)2 (2) as 2·0.75H 2O, which was structurally characterized with X-ray crystallography (P212121, R1 = 0.0321, wR 2 = 0.0622). Compound 2 shows an approximate non-crystallographic twofold axis. The packing in the crystalline state is dictated by the mediation of crystallization water molecules, which connect the complex units through strong O-H⋯S and weak C-H⋯O hydrogen bonds into infinite zigzag chains.",

keywords = "Dimethyldithioarsinato ligand, Gallium, X-ray crystallography",

author = "Constantina Papatriantafyllopoulou and Vassilios Nastopoulos and Ioannou, \{Panayiotis V.\}",

year = "2014",

month = jul,

doi = "10.1002/zaac.201400076",

language = "English",

volume = "640",

pages = "1654--1657",

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number = "8-9",

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Papatriantafyllopoulou, C, Nastopoulos, V & Ioannou, PV 2014, 'The structure of bis(dimethyldithioarsinato)gallium(III) sulfide [(Me ₂AsS₂)₂Ga]₂S·0.75H ₂O: A hydrolysis product of (Me₂AsS₂) ₃Ga that contains a bridging sulfide and both pendant and bridging dimethyldithioarsinato ligands', Zeitschrift fur Anorganische und Allgemeine Chemie, vol. 640, no. 8-9, pp. 1654-1657. https://doi.org/10.1002/zaac.201400076

The structure of bis(dimethyldithioarsinato)gallium(III) sulfide [(Me ₂AsS₂)₂Ga]₂S·0.75H ₂O: A hydrolysis product of (Me₂AsS₂) ₃Ga that contains a bridging sulfide and both pendant and bridging dimethyldithioarsinato ligands. / Papatriantafyllopoulou, Constantina; Nastopoulos, Vassilios; Ioannou, Panayiotis V.
In: Zeitschrift fur Anorganische und Allgemeine Chemie, Vol. 640, No. 8-9, 07.2014, p. 1654-1657.

Research output: Contribution to a Journal (Peer & Non Peer) › Article › peer-review

TY - JOUR

T1 - The structure of bis(dimethyldithioarsinato)gallium(III) sulfide [(Me 2AsS2)2Ga]2S·0.75H 2O

T2 - A hydrolysis product of (Me2AsS2) 3Ga that contains a bridging sulfide and both pendant and bridging dimethyldithioarsinato ligands

AU - Papatriantafyllopoulou, Constantina

AU - Nastopoulos, Vassilios

AU - Ioannou, Panayiotis V.

PY - 2014/7

Y1 - 2014/7

N2 - The complex (Me2AsS2)3Ga (1) attracted water molecules that slowly and completely hydrolyzed it. The product was the dinuclear gallium compound (Me2AsS2)2Ga-S- Ga(S2AsMe2)2 (2) as 2·0.75H 2O, which was structurally characterized with X-ray crystallography (P212121, R1 = 0.0321, wR 2 = 0.0622). Compound 2 shows an approximate non-crystallographic twofold axis. The packing in the crystalline state is dictated by the mediation of crystallization water molecules, which connect the complex units through strong O-H⋯S and weak C-H⋯O hydrogen bonds into infinite zigzag chains.

AB - The complex (Me2AsS2)3Ga (1) attracted water molecules that slowly and completely hydrolyzed it. The product was the dinuclear gallium compound (Me2AsS2)2Ga-S- Ga(S2AsMe2)2 (2) as 2·0.75H 2O, which was structurally characterized with X-ray crystallography (P212121, R1 = 0.0321, wR 2 = 0.0622). Compound 2 shows an approximate non-crystallographic twofold axis. The packing in the crystalline state is dictated by the mediation of crystallization water molecules, which connect the complex units through strong O-H⋯S and weak C-H⋯O hydrogen bonds into infinite zigzag chains.

KW - Dimethyldithioarsinato ligand

KW - Gallium

KW - X-ray crystallography

UR - https://www.scopus.com/pages/publications/84904515495

U2 - 10.1002/zaac.201400076

DO - 10.1002/zaac.201400076

M3 - Article

SN - 0044-2313

VL - 640

SP - 1654

EP - 1657

JO - Zeitschrift fur Anorganische und Allgemeine Chemie

JF - Zeitschrift fur Anorganische und Allgemeine Chemie

IS - 8-9

ER -

Papatriantafyllopoulou C, Nastopoulos V, Ioannou PV. The structure of bis(dimethyldithioarsinato)gallium(III) sulfide [(Me ₂AsS₂)₂Ga]₂S·0.75H ₂O: A hydrolysis product of (Me₂AsS₂) ₃Ga that contains a bridging sulfide and both pendant and bridging dimethyldithioarsinato ligands. Zeitschrift fur Anorganische und Allgemeine Chemie. 2014 Jul;640(8-9):1654-1657. doi: 10.1002/zaac.201400076