The solution structure and fluxional behaviour of cyclic and acyclic (diene)Fe(CO)2L complexes (L = phosphine, phosphite, isonitrile)

James A.S. Howell; Gary Walton; Marie Claire Tirvengadum; Adrian D. Squibb; Michael G. Palin; Patrick McArdle; Desmond Cunningham; Zeev Goldschmidt; Hugo Gottlieb; Gila Strul

doi:10.1016/0022-328X(91)86199-Z

The solution structure and fluxional behaviour of cyclic and acyclic (diene)Fe(CO)₂L complexes (L = phosphine, phosphite, isonitrile)

James A.S. Howell
, Gary Walton
, Marie Claire Tirvengadum
, Adrian D. Squibb
, Michael G. Palin
, Patrick McArdle
, Desmond Cunningham
, Zeev Goldschmidt
, Hugo Gottlieb
, Gila Strul

Research output: Contribution to a Journal (Peer & Non Peer) › Article › peer-review

26 Citations (Scopus)

Abstract

Variable temperature ¹³C and ³¹P NMR spectroscopy has been used to establish solution structures and conformer populations for a variety of cylic and acyclic (diene)Fe(CO)₂L complexes (L = phosphine, phosphite, isonitrile). The solid state structures of (2,3-dimethylbutadiene)Fe(CO)₂PPh₃ and (trans,trans-2,4-hexadiene)Fe(CO)₂PPh₃ have been determined and used as a basis for molecular modelling of steric effects in these complexes.

Original language	English
Pages (from-to)	91-123
Number of pages	33
Journal	Journal of Organometallic Chemistry
Volume	401
Issue number	1-2
DOIs	https://doi.org/10.1016/0022-328X(91)86199-Z
Publication status	Published - 8 Jan 1991
Externally published	Yes

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10.1016/0022-328X(91)86199-Z

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Howell, J. A. S., Walton, G., Tirvengadum, M. C., Squibb, A. D., Palin, M. G., McArdle, P., Cunningham, D., Goldschmidt, Z., Gottlieb, H., & Strul, G. (1991). The solution structure and fluxional behaviour of cyclic and acyclic (diene)Fe(CO)₂L complexes (L = phosphine, phosphite, isonitrile). Journal of Organometallic Chemistry, 401(1-2), 91-123. https://doi.org/10.1016/0022-328X(91)86199-Z

@article{84166b4021a247368cb173e78ddcb860,

title = "The solution structure and fluxional behaviour of cyclic and acyclic (diene)Fe(CO)2L complexes (L = phosphine, phosphite, isonitrile)",

abstract = "Variable temperature 13C and 31P NMR spectroscopy has been used to establish solution structures and conformer populations for a variety of cylic and acyclic (diene)Fe(CO)2L complexes (L = phosphine, phosphite, isonitrile). The solid state structures of (2,3-dimethylbutadiene)Fe(CO)2PPh3 and (trans,trans-2,4-hexadiene)Fe(CO)2PPh3 have been determined and used as a basis for molecular modelling of steric effects in these complexes.",

author = "Howell, \{James A.S.\} and Gary Walton and Tirvengadum, \{Marie Claire\} and Squibb, \{Adrian D.\} and Palin, \{Michael G.\} and Patrick McArdle and Desmond Cunningham and Zeev Goldschmidt and Hugo Gottlieb and Gila Strul",

year = "1991",

month = jan,

day = "8",

doi = "10.1016/0022-328X(91)86199-Z",

language = "English",

volume = "401",

pages = "91--123",

journal = "Journal of Organometallic Chemistry",

issn = "0022-328X",

publisher = "Elsevier B.V.",

number = "1-2",

}

Howell, JAS, Walton, G, Tirvengadum, MC, Squibb, AD, Palin, MG, McArdle, P, Cunningham, D, Goldschmidt, Z, Gottlieb, H & Strul, G 1991, 'The solution structure and fluxional behaviour of cyclic and acyclic (diene)Fe(CO)₂L complexes (L = phosphine, phosphite, isonitrile)', Journal of Organometallic Chemistry, vol. 401, no. 1-2, pp. 91-123. https://doi.org/10.1016/0022-328X(91)86199-Z

The solution structure and fluxional behaviour of cyclic and acyclic (diene)Fe(CO)₂L complexes (L = phosphine, phosphite, isonitrile). / Howell, James A.S.; Walton, Gary; Tirvengadum, Marie Claire et al.
In: Journal of Organometallic Chemistry, Vol. 401, No. 1-2, 08.01.1991, p. 91-123.

Research output: Contribution to a Journal (Peer & Non Peer) › Article › peer-review

TY - JOUR

T1 - The solution structure and fluxional behaviour of cyclic and acyclic (diene)Fe(CO)2L complexes (L = phosphine, phosphite, isonitrile)

AU - Howell, James A.S.

AU - Walton, Gary

AU - Tirvengadum, Marie Claire

AU - Squibb, Adrian D.

AU - Palin, Michael G.

AU - McArdle, Patrick

AU - Cunningham, Desmond

AU - Goldschmidt, Zeev

AU - Gottlieb, Hugo

AU - Strul, Gila

PY - 1991/1/8

Y1 - 1991/1/8

N2 - Variable temperature 13C and 31P NMR spectroscopy has been used to establish solution structures and conformer populations for a variety of cylic and acyclic (diene)Fe(CO)2L complexes (L = phosphine, phosphite, isonitrile). The solid state structures of (2,3-dimethylbutadiene)Fe(CO)2PPh3 and (trans,trans-2,4-hexadiene)Fe(CO)2PPh3 have been determined and used as a basis for molecular modelling of steric effects in these complexes.

AB - Variable temperature 13C and 31P NMR spectroscopy has been used to establish solution structures and conformer populations for a variety of cylic and acyclic (diene)Fe(CO)2L complexes (L = phosphine, phosphite, isonitrile). The solid state structures of (2,3-dimethylbutadiene)Fe(CO)2PPh3 and (trans,trans-2,4-hexadiene)Fe(CO)2PPh3 have been determined and used as a basis for molecular modelling of steric effects in these complexes.

UR - https://www.scopus.com/pages/publications/0002308220

U2 - 10.1016/0022-328X(91)86199-Z

DO - 10.1016/0022-328X(91)86199-Z

M3 - Article

SN - 0022-328X

VL - 401

SP - 91

EP - 123

JO - Journal of Organometallic Chemistry

JF - Journal of Organometallic Chemistry

IS - 1-2

ER -

The solution structure and fluxional behaviour of cyclic and acyclic (diene)Fe(CO)₂L complexes (L = phosphine, phosphite, isonitrile)

Abstract

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