Abstract
Variable temperature C-13 and P-31 NMR spectroscopy has been used to establish solution structures and conformer populations for a variety of cyclic and acyclic (diene)Fe(CO)2L complexes (L = phosphine, phosphite, isonitrile). The solid state structures of (2,3-dimethylbutadiene)Fe(CO)2 PPh3 and (trans,trans-2,4-hexadiene)Fe(CO)2PPh3 have been determined and used as a basis for molecular modelling of steric effects in these complexes.
| Original language | English (Ireland) |
|---|---|
| Number of pages | 33 |
| Journal | Journal Of Organometallic Chemistry |
| Volume | 401 |
| Publication status | Published - 1 Jan 1991 |
Authors (Note for portal: view the doc link for the full list of authors)
- Authors
- HOWELL, JAS,WALTON, G,TIRVENGADUM, MC,SQUIBB, AD,PALIN, MG,MCARDLE, P,CUNNINGHAM, D,GOLDSCHMIDT, Z,GOTTLIEB, H,STRUL, G