The influence of local coordination ions on the optical properties of Eu3+ in fluoro-chloride glasses

R. Balda; J. Fernández; A. J. García; G. F. Imbusch

doi:10.1016/S0022-2313(97)00249-4

The influence of local coordination ions on the optical properties of Eu³⁺ in fluoro-chloride glasses

R. Balda, J. Fernández, A. J. García, G. F. Imbusch

Physics

University of Basque

Research output: Contribution to a Journal (Peer & Non Peer) › Article › peer-review

4 Citations (Scopus)

Abstract

The influence of the local coordination ions on the optical properties of Eu^3- in fluoro-chloride glasses has been investigated by means of fluorescence line-narrowing spectroscopy. The decay of the line-narrowed fluorescence of the ⁵Do → ⁷F₂ hypersensitive transition, the line width of the line narrowed ⁵D₀ → ⁷F₀ emission, and the average strength of the crystal field measured as a function of excitation energy along the ⁷F₀ → ⁵F₀ absorption can be interpreted as indicating a crossover between the behaviour of fluorine-like and chlorine-like coordination anions.

Original language	English
Pages (from-to)	551-554
Number of pages	4
Journal	Journal of Luminescence
Volume	76-77
DOIs	https://doi.org/10.1016/S0022-2313(97)00249-4
Publication status	Published - Feb 1998

Keywords

Fluorescence line narrowing
Glasses
Rare-earth ion

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10.1016/S0022-2313(97)00249-4

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title = "The influence of local coordination ions on the optical properties of Eu3+ in fluoro-chloride glasses",

abstract = "The influence of the local coordination ions on the optical properties of Eu3- in fluoro-chloride glasses has been investigated by means of fluorescence line-narrowing spectroscopy. The decay of the line-narrowed fluorescence of the 5Do → 7F2 hypersensitive transition, the line width of the line narrowed 5D0 → 7F0 emission, and the average strength of the crystal field measured as a function of excitation energy along the 7F0 → 5F0 absorption can be interpreted as indicating a crossover between the behaviour of fluorine-like and chlorine-like coordination anions.",

keywords = "Fluorescence line narrowing, Glasses, Rare-earth ion",

author = "R. Balda and J. Fern{\'a}ndez and Garc{\'i}a, \{A. J.\} and Imbusch, \{G. F.\}",

year = "1998",

month = feb,

doi = "10.1016/S0022-2313(97)00249-4",

language = "English",

volume = "76-77",

pages = "551--554",

journal = "Journal of Luminescence",

issn = "0022-2313",

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T1 - The influence of local coordination ions on the optical properties of Eu3+ in fluoro-chloride glasses

AU - Balda, R.

AU - Fernández, J.

AU - García, A. J.

AU - Imbusch, G. F.

PY - 1998/2

Y1 - 1998/2

N2 - The influence of the local coordination ions on the optical properties of Eu3- in fluoro-chloride glasses has been investigated by means of fluorescence line-narrowing spectroscopy. The decay of the line-narrowed fluorescence of the 5Do → 7F2 hypersensitive transition, the line width of the line narrowed 5D0 → 7F0 emission, and the average strength of the crystal field measured as a function of excitation energy along the 7F0 → 5F0 absorption can be interpreted as indicating a crossover between the behaviour of fluorine-like and chlorine-like coordination anions.

AB - The influence of the local coordination ions on the optical properties of Eu3- in fluoro-chloride glasses has been investigated by means of fluorescence line-narrowing spectroscopy. The decay of the line-narrowed fluorescence of the 5Do → 7F2 hypersensitive transition, the line width of the line narrowed 5D0 → 7F0 emission, and the average strength of the crystal field measured as a function of excitation energy along the 7F0 → 5F0 absorption can be interpreted as indicating a crossover between the behaviour of fluorine-like and chlorine-like coordination anions.

KW - Fluorescence line narrowing

KW - Glasses

KW - Rare-earth ion

UR - https://www.scopus.com/pages/publications/0042355734

U2 - 10.1016/S0022-2313(97)00249-4

DO - 10.1016/S0022-2313(97)00249-4

M3 - Article

AN - SCOPUS:0042355734

SN - 0022-2313

VL - 76-77

SP - 551

EP - 554

JO - Journal of Luminescence

JF - Journal of Luminescence

ER -

The influence of local coordination ions on the optical properties of Eu³⁺ in fluoro-chloride glasses

Abstract

Keywords

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