The comparison of detailed chemical kinetic mechanisms: Application to the combustion of methane: Application to the combustion of methane

Detailed chemical kinetic mechanisms of complex chemical phenomena may be composed of hundreds of species and thousands of individual elementary reactions. It can be an extremely laborious and error-prone procedure to compare two of these mechanisms, particularly if they come from different sources. We have created software tools which help to highlight the differences between mechanisms written in a Chemkin format and demonstrate their applicability to five literature mechanisms describing the high temperature oxidation of methane. (C) 2004 Wiley Periodicals, Inc.