Synthesis, structures, and electroluminescence properties of a 1D zinc(II) coordination polymer containing both dicyanamide and pyrazinamide ligands

Leila Tabrizi; Hossein Chiniforoshan; Patrick McArdle

doi:10.1080/00958972.2015.1036749

Synthesis, structures, and electroluminescence properties of a 1D zinc(II) coordination polymer containing both dicyanamide and pyrazinamide ligands

Leila Tabrizi, Hossein Chiniforoshan, Patrick McArdle

Research output: Contribution to a Journal (Peer & Non Peer) › Article › peer-review

7 Citations (Scopus)

Abstract

A 1D coordination polymer, {[Zn(μ_1,5-dca)₂(PZA)₂](PZA)₂}_n (1), has been synthesized and characterized by single-crystal X-ray crystallography. The coordination modes of the dicyanamide (dca) and the pyrazinamide (PZA) were inferred by IR spectroscopy. The complex was applied to organic electroluminescent (EL) devices as the emitting materials. The electroluminescent device of ITO/NPB (40 nm)/Zn polymer: CBP (30 nm) (30 nm)/BCP (15 nm)/Alq (30 nm)/LiF (1 nm)/Al (100 nm) was fabricated. The EL device emits cyan light originating from this complex with high brightness and efficiencies. For 1, a maximum luminance of 34.9 cd/A was achieved at 9 V.

Original language	English
Pages (from-to)	1936-1946
Number of pages	11
Journal	Journal of Coordination Chemistry
Volume	68
Issue number	11
DOIs	https://doi.org/10.1080/00958972.2015.1036749
Publication status	Published - 3 Jun 2015
Externally published	Yes

Keywords

Dicyanamide
Electroluminescence
Pyrazinamide
Zinc(II)

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10.1080/00958972.2015.1036749

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title = "Synthesis, structures, and electroluminescence properties of a 1D zinc(II) coordination polymer containing both dicyanamide and pyrazinamide ligands",

abstract = "A 1D coordination polymer, \{[Zn(μ1,5-dca)2(PZA)2](PZA)2\}n (1), has been synthesized and characterized by single-crystal X-ray crystallography. The coordination modes of the dicyanamide (dca) and the pyrazinamide (PZA) were inferred by IR spectroscopy. The complex was applied to organic electroluminescent (EL) devices as the emitting materials. The electroluminescent device of ITO/NPB (40 nm)/Zn polymer: CBP (30 nm) (30 nm)/BCP (15 nm)/Alq (30 nm)/LiF (1 nm)/Al (100 nm) was fabricated. The EL device emits cyan light originating from this complex with high brightness and efficiencies. For 1, a maximum luminance of 34.9 cd/A was achieved at 9 V.",

keywords = "Dicyanamide, Electroluminescence, Pyrazinamide, Zinc(II)",

author = "Leila Tabrizi and Hossein Chiniforoshan and Patrick McArdle",

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doi = "10.1080/00958972.2015.1036749",

language = "English",

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Synthesis, structures, and electroluminescence properties of a 1D zinc(II) coordination polymer containing both dicyanamide and pyrazinamide ligands. / Tabrizi, Leila; Chiniforoshan, Hossein; McArdle, Patrick.
In: Journal of Coordination Chemistry, Vol. 68, No. 11, 03.06.2015, p. 1936-1946.

Research output: Contribution to a Journal (Peer & Non Peer) › Article › peer-review

TY - JOUR

T1 - Synthesis, structures, and electroluminescence properties of a 1D zinc(II) coordination polymer containing both dicyanamide and pyrazinamide ligands

AU - Tabrizi, Leila

AU - Chiniforoshan, Hossein

AU - McArdle, Patrick

PY - 2015/6/3

Y1 - 2015/6/3

N2 - A 1D coordination polymer, {[Zn(μ1,5-dca)2(PZA)2](PZA)2}n (1), has been synthesized and characterized by single-crystal X-ray crystallography. The coordination modes of the dicyanamide (dca) and the pyrazinamide (PZA) were inferred by IR spectroscopy. The complex was applied to organic electroluminescent (EL) devices as the emitting materials. The electroluminescent device of ITO/NPB (40 nm)/Zn polymer: CBP (30 nm) (30 nm)/BCP (15 nm)/Alq (30 nm)/LiF (1 nm)/Al (100 nm) was fabricated. The EL device emits cyan light originating from this complex with high brightness and efficiencies. For 1, a maximum luminance of 34.9 cd/A was achieved at 9 V.

AB - A 1D coordination polymer, {[Zn(μ1,5-dca)2(PZA)2](PZA)2}n (1), has been synthesized and characterized by single-crystal X-ray crystallography. The coordination modes of the dicyanamide (dca) and the pyrazinamide (PZA) were inferred by IR spectroscopy. The complex was applied to organic electroluminescent (EL) devices as the emitting materials. The electroluminescent device of ITO/NPB (40 nm)/Zn polymer: CBP (30 nm) (30 nm)/BCP (15 nm)/Alq (30 nm)/LiF (1 nm)/Al (100 nm) was fabricated. The EL device emits cyan light originating from this complex with high brightness and efficiencies. For 1, a maximum luminance of 34.9 cd/A was achieved at 9 V.

KW - Dicyanamide

KW - Electroluminescence

KW - Pyrazinamide

KW - Zinc(II)

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DO - 10.1080/00958972.2015.1036749

M3 - Article

SN - 0095-8972

VL - 68

SP - 1936

EP - 1946

JO - Journal of Coordination Chemistry

JF - Journal of Coordination Chemistry

IS - 11

ER -

Synthesis, structures, and electroluminescence properties of a 1D zinc(II) coordination polymer containing both dicyanamide and pyrazinamide ligands

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Keywords

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