Synthesis of novel chiral cyclopentadienes: Synthesis of chiral iron complexes and the crystal structures of [(eta(5)-(1S)-1-(6-methoxynaphthalenyl)-1-(tetramethyl cyclopentadienyl)ethane)Fe(CO)(2)SnCl3] and [(eta(5)-C-5(Me)(4)C(H)(CH3)(C2H5))Fe(CO)-(eta(4)-diphenylbutadiene)](+)[BF4](-)

Patrick Mcardle

Synthesis of novel chiral cyclopentadienes: Synthesis of chiral iron complexes and the crystal structures of [(eta(5)-(1S)-1-(6-methoxynaphthalenyl)-1-(tetramethyl cyclopentadienyl)ethane)Fe(CO)(2)SnCl3] and [(eta(5)-C-5(Me)(4)C(H)(CH3)(C2H5))Fe(CO)-(eta(4)-diphenylbutadiene)](+)[BF4](-)

Patrick Mcardle

Cellular & Molecular Medicine

Research output: Contribution to a Journal (Peer & Non Peer) › Article › peer-review

Abstract

Two new functionalized tetramethylcyclopentadiene (FTMCP) ligands are described: optically active (1S)-1-(6-methoxynaphthalenyl)-1-(2,3,4,5-tetramethylcyclopentadienyl)-ethane (2) and racemic 1-methyl-1-(2,3,4,5-TMCP)propane (3). These ligands were used to synthesize cationic diene complexes [(eta(5)-FTMCP)Fe(CO)(eta(4)-diene)](+)[BF4](-)(diene=diphenylbutadiene (11), methyl hexa-2,4-dienoate (10)). The absolute configuration of the ligand 2 was determined from the crystal structure of complex [(eta(5)-(1S)-1-(6-methoxynaphthalenyl)1-(2,3,4,5-tetramethylcyclopentadienyl)-(8).

Original language	English (Ireland)
Journal	Organometallics
Volume	16
Publication status	Published - 1 Jun 1997

Authors (Note for portal: view the doc link for the full list of authors)

Authors
McArdle, P, Ryder, AG,Cunningham, D

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@article{dd93e3765d6e4128885edfc0f217a846,

title = "Synthesis of novel chiral cyclopentadienes: Synthesis of chiral iron complexes and the crystal structures of [(eta(5)-(1S)-1-(6-methoxynaphthalenyl)-1-(tetramethyl cyclopentadienyl)ethane)Fe(CO)(2)SnCl3] and [(eta(5)-C-5(Me)(4)C(H)(CH3)(C2H5))Fe(CO)-(eta(4)-diphenylbutadiene)](+)[BF4](-)",

abstract = "Two new functionalized tetramethylcyclopentadiene (FTMCP) ligands are described: optically active (1S)-1-(6-methoxynaphthalenyl)-1-(2,3,4,5-tetramethylcyclopentadienyl)-ethane (2) and racemic 1-methyl-1-(2,3,4,5-TMCP)propane (3). These ligands were used to synthesize cationic diene complexes [(eta(5)-FTMCP)Fe(CO)(eta(4)-diene)](+)[BF4](-)(diene=diphenylbutadiene (11), methyl hexa-2,4-dienoate (10)). The absolute configuration of the ligand 2 was determined from the crystal structure of complex [(eta(5)-(1S)-1-(6-methoxynaphthalenyl)1-(2,3,4,5-tetramethylcyclopentadienyl)-(8).",

author = "Patrick Mcardle",

year = "1997",

month = jun,

day = "1",

language = "English (Ireland)",

volume = "16",

journal = "Organometallics",

}

Synthesis of novel chiral cyclopentadienes: Synthesis of chiral iron complexes and the crystal structures of [(eta(5)-(1S)-1-(6-methoxynaphthalenyl)-1-(tetramethyl cyclopentadienyl)ethane)Fe(CO)(2)SnCl3] and [(eta(5)-C-5(Me)(4)C(H)(CH3)(C2H5))Fe(CO)-(eta(4)-diphenylbutadiene)](+)[BF4](-). / Mcardle, Patrick.
In: Organometallics, Vol. 16, 01.06.1997.

Research output: Contribution to a Journal (Peer & Non Peer) › Article › peer-review

TY - JOUR

T1 - Synthesis of novel chiral cyclopentadienes: Synthesis of chiral iron complexes and the crystal structures of [(eta(5)-(1S)-1-(6-methoxynaphthalenyl)-1-(tetramethyl cyclopentadienyl)ethane)Fe(CO)(2)SnCl3] and [(eta(5)-C-5(Me)(4)C(H)(CH3)(C2H5))Fe(CO)-(eta(4)-diphenylbutadiene)](+)[BF4](-)

AU - Mcardle, Patrick

PY - 1997/6/1

Y1 - 1997/6/1

N2 - Two new functionalized tetramethylcyclopentadiene (FTMCP) ligands are described: optically active (1S)-1-(6-methoxynaphthalenyl)-1-(2,3,4,5-tetramethylcyclopentadienyl)-ethane (2) and racemic 1-methyl-1-(2,3,4,5-TMCP)propane (3). These ligands were used to synthesize cationic diene complexes [(eta(5)-FTMCP)Fe(CO)(eta(4)-diene)](+)[BF4](-)(diene=diphenylbutadiene (11), methyl hexa-2,4-dienoate (10)). The absolute configuration of the ligand 2 was determined from the crystal structure of complex [(eta(5)-(1S)-1-(6-methoxynaphthalenyl)1-(2,3,4,5-tetramethylcyclopentadienyl)-(8).

AB - Two new functionalized tetramethylcyclopentadiene (FTMCP) ligands are described: optically active (1S)-1-(6-methoxynaphthalenyl)-1-(2,3,4,5-tetramethylcyclopentadienyl)-ethane (2) and racemic 1-methyl-1-(2,3,4,5-TMCP)propane (3). These ligands were used to synthesize cationic diene complexes [(eta(5)-FTMCP)Fe(CO)(eta(4)-diene)](+)[BF4](-)(diene=diphenylbutadiene (11), methyl hexa-2,4-dienoate (10)). The absolute configuration of the ligand 2 was determined from the crystal structure of complex [(eta(5)-(1S)-1-(6-methoxynaphthalenyl)1-(2,3,4,5-tetramethylcyclopentadienyl)-(8).

M3 - Article

VL - 16

JO - Organometallics

JF - Organometallics

ER -