Synthesis, crystal structure and solution behavior of a novel tetranuclear Zn(II) Schiff base complex

Jolante Hermann; Andrea Erxleben

doi:10.1016/S0020-1693(00)00064-5

Synthesis, crystal structure and solution behavior of a novel tetranuclear Zn(II) Schiff base complex

Jolante Hermann
, Andrea Erxleben

Technische Universität Dortmund

Research output: Contribution to a Journal (Peer & Non Peer) › Article › peer-review

24 Citations (Scopus)

Abstract

The tetranuclear Zn(II) Schiff base complex [Mg(H₂O)₆][{Zn₂L¹(CH₃CO₂)}₂(μ₃-OH)₂]·6H₂O (H₃L¹ = Schiff base derived from 2,6-diformyl-4-methylphenol and glycine) (2) has been prepared and structurally characterized. The complex anion consists of two identical dinuclear Zn₂/L¹ subunits connected through μ₃-OH bridges. While 2, with Mg(H₂O)₆/²⁺ serving as counterion, crystallized from aqueous solution, solution studies in DMSO indicated substitution of zinc by magnesium and formation of the heteronuclear complex [ZnMgL¹]⁺. (C) 2000 Elsevier Science S.A.

Original language	English
Pages (from-to)	125-129
Number of pages	5
Journal	Inorganica Chimica Acta
Volume	304
Issue number	1
DOIs	https://doi.org/10.1016/S0020-1693(00)00064-5
Publication status	Published - 15 Jun 2000
Externally published	Yes

Keywords

Crystal structures
Schiff base complexes
Zinc complexes

Access to Document

10.1016/S0020-1693(00)00064-5

Cite this

@article{0d8b223481ef49189633dc896b66b335,

title = "Synthesis, crystal structure and solution behavior of a novel tetranuclear Zn(II) Schiff base complex",

abstract = "The tetranuclear Zn(II) Schiff base complex [Mg(H2O)6][\{Zn2L1(CH3CO2)\}2(μ3-OH)2]·6H2O (H3L1 = Schiff base derived from 2,6-diformyl-4-methylphenol and glycine) (2) has been prepared and structurally characterized. The complex anion consists of two identical dinuclear Zn2/L1 subunits connected through μ3-OH bridges. While 2, with Mg(H2O)6/2+ serving as counterion, crystallized from aqueous solution, solution studies in DMSO indicated substitution of zinc by magnesium and formation of the heteronuclear complex [ZnMgL1]+. (C) 2000 Elsevier Science S.A.",

keywords = "Crystal structures, Schiff base complexes, Zinc complexes",

author = "Jolante Hermann and Andrea Erxleben",

year = "2000",

month = jun,

day = "15",

doi = "10.1016/S0020-1693(00)00064-5",

language = "English",

volume = "304",

pages = "125--129",

journal = "Inorganica Chimica Acta",

issn = "0020-1693",

publisher = "Elsevier B.V.",

number = "1",

}

TY - JOUR

T1 - Synthesis, crystal structure and solution behavior of a novel tetranuclear Zn(II) Schiff base complex

AU - Hermann, Jolante

AU - Erxleben, Andrea

PY - 2000/6/15

Y1 - 2000/6/15

N2 - The tetranuclear Zn(II) Schiff base complex [Mg(H2O)6][{Zn2L1(CH3CO2)}2(μ3-OH)2]·6H2O (H3L1 = Schiff base derived from 2,6-diformyl-4-methylphenol and glycine) (2) has been prepared and structurally characterized. The complex anion consists of two identical dinuclear Zn2/L1 subunits connected through μ3-OH bridges. While 2, with Mg(H2O)6/2+ serving as counterion, crystallized from aqueous solution, solution studies in DMSO indicated substitution of zinc by magnesium and formation of the heteronuclear complex [ZnMgL1]+. (C) 2000 Elsevier Science S.A.

AB - The tetranuclear Zn(II) Schiff base complex [Mg(H2O)6][{Zn2L1(CH3CO2)}2(μ3-OH)2]·6H2O (H3L1 = Schiff base derived from 2,6-diformyl-4-methylphenol and glycine) (2) has been prepared and structurally characterized. The complex anion consists of two identical dinuclear Zn2/L1 subunits connected through μ3-OH bridges. While 2, with Mg(H2O)6/2+ serving as counterion, crystallized from aqueous solution, solution studies in DMSO indicated substitution of zinc by magnesium and formation of the heteronuclear complex [ZnMgL1]+. (C) 2000 Elsevier Science S.A.

KW - Crystal structures

KW - Schiff base complexes

KW - Zinc complexes

UR - https://www.scopus.com/pages/publications/0034658994

U2 - 10.1016/S0020-1693(00)00064-5

DO - 10.1016/S0020-1693(00)00064-5

M3 - Article

SN - 0020-1693

VL - 304

SP - 125

EP - 129

JO - Inorganica Chimica Acta

JF - Inorganica Chimica Acta

IS - 1

ER -

Synthesis, crystal structure and solution behavior of a novel tetranuclear Zn(II) Schiff base complex

Abstract

Keywords

Access to Document

Other files and links

Fingerprint

Cite this