Synthesis, characterization, and molecular structures of Ni(II) and Cd(II) complexes derived from dithiophosphonate

Alireza Banaei; Afshin Saadat; Mina Mohammad Goli; Patrick McArdle; Eslam Pourbasheer; Parinaz Pargolghasemi

doi:10.1002/hc.21345

Synthesis, characterization, and molecular structures of Ni(II) and Cd(II) complexes derived from dithiophosphonate

Alireza Banaei, Afshin Saadat, Mina Mohammad Goli, Patrick McArdle, Eslam Pourbasheer, Parinaz Pargolghasemi

Research output: Contribution to a Journal (Peer & Non Peer) › Article › peer-review

7 Citations (Scopus)

Abstract

Two novel dithiophosphonate ligands, HS₂P(p-C₆H₄OMe)(OCH₂CH₂CH(CH₃)₂) (1) and HS₂P(p-C₆H₄OMe)(OCH(CH₃)₂) (2), were synthesized and characterized by multinuclear (¹H, ³¹P, and ¹³C) NMR, infrared spectroscopy as well as elemental analysis. The reactions of 1 and 2 with NiCl₂·6H₂O and Cd(NO₃)₂·4H₂O in methanol led to novel complexes 3 and 4. The single crystal X-ray structures of 3 and 4 showed tetracoordinated structure with square planar geometry for the nickel complex, while it showed pentacoordinated structure with distorted square-pyramid environment for the cadmium complex.

Original language	English
Pages (from-to)	353-360
Number of pages	8
Journal	Heteroatom Chemistry
Volume	27
Issue number	6
DOIs	https://doi.org/10.1002/hc.21345
Publication status	Published - 1 Nov 2016
Externally published	Yes

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title = "Synthesis, characterization, and molecular structures of Ni(II) and Cd(II) complexes derived from dithiophosphonate",

abstract = "Two novel dithiophosphonate ligands, HS2P(p-C6H4OMe)(OCH2CH2CH(CH3)2) (1) and HS2P(p-C6H4OMe)(OCH(CH3)2) (2), were synthesized and characterized by multinuclear (1H, 31P, and 13C) NMR, infrared spectroscopy as well as elemental analysis. The reactions of 1 and 2 with NiCl2·6H2O and Cd(NO3)2·4H2O in methanol led to novel complexes 3 and 4. The single crystal X-ray structures of 3 and 4 showed tetracoordinated structure with square planar geometry for the nickel complex, while it showed pentacoordinated structure with distorted square-pyramid environment for the cadmium complex.",

author = "Alireza Banaei and Afshin Saadat and {Mohammad Goli}, Mina and Patrick McArdle and Eslam Pourbasheer and Parinaz Pargolghasemi",

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doi = "10.1002/hc.21345",

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T1 - Synthesis, characterization, and molecular structures of Ni(II) and Cd(II) complexes derived from dithiophosphonate

AU - Banaei, Alireza

AU - Saadat, Afshin

AU - Mohammad Goli, Mina

AU - McArdle, Patrick

AU - Pourbasheer, Eslam

AU - Pargolghasemi, Parinaz

PY - 2016/11/1

Y1 - 2016/11/1

N2 - Two novel dithiophosphonate ligands, HS2P(p-C6H4OMe)(OCH2CH2CH(CH3)2) (1) and HS2P(p-C6H4OMe)(OCH(CH3)2) (2), were synthesized and characterized by multinuclear (1H, 31P, and 13C) NMR, infrared spectroscopy as well as elemental analysis. The reactions of 1 and 2 with NiCl2·6H2O and Cd(NO3)2·4H2O in methanol led to novel complexes 3 and 4. The single crystal X-ray structures of 3 and 4 showed tetracoordinated structure with square planar geometry for the nickel complex, while it showed pentacoordinated structure with distorted square-pyramid environment for the cadmium complex.

AB - Two novel dithiophosphonate ligands, HS2P(p-C6H4OMe)(OCH2CH2CH(CH3)2) (1) and HS2P(p-C6H4OMe)(OCH(CH3)2) (2), were synthesized and characterized by multinuclear (1H, 31P, and 13C) NMR, infrared spectroscopy as well as elemental analysis. The reactions of 1 and 2 with NiCl2·6H2O and Cd(NO3)2·4H2O in methanol led to novel complexes 3 and 4. The single crystal X-ray structures of 3 and 4 showed tetracoordinated structure with square planar geometry for the nickel complex, while it showed pentacoordinated structure with distorted square-pyramid environment for the cadmium complex.

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DO - 10.1002/hc.21345

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JO - Heteroatom Chemistry

JF - Heteroatom Chemistry

IS - 6

ER -

Synthesis, characterization, and molecular structures of Ni(II) and Cd(II) complexes derived from dithiophosphonate

Abstract

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