Synthesis and X-ray single crystal structure of a bivalent glycocluster

Manuela Tosin; Helge Müller-Bunz; Paul V. Murphy

doi:10.1039/b313934d

Synthesis and X-ray single crystal structure of a bivalent glycocluster

Manuela Tosin
, Helge Müller-Bunz
, Paul V. Murphy

University College Dublin

Research output: Contribution to a Journal (Peer & Non Peer) › Article › peer-review

11 Citations (Scopus)

Abstract

The crystal structure of a bivalent glycocluster containing aromatic amides reveals that alkylation of secondary amides alters amide configuration and thus carbohydrate presentation. This also facilitates non covalent interactions (azide–azide, carbonyl–pyranose and aromatic–pyranose) and thus carbohydrate–carbohydrate stacking.

Original language	English
Pages (from-to)	494-495
Number of pages	2
Journal	Chemical Communications
Volume	4
Issue number	5
DOIs	https://doi.org/10.1039/b313934d
Publication status	Published - 2004
Externally published	Yes

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10.1039/b313934d

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title = "Synthesis and X-ray single crystal structure of a bivalent glycocluster",

abstract = "The crystal structure of a bivalent glycocluster containing aromatic amides reveals that alkylation of secondary amides alters amide configuration and thus carbohydrate presentation. This also facilitates non covalent interactions (azide{\textendash}azide, carbonyl{\textendash}pyranose and aromatic{\textendash}pyranose) and thus carbohydrate{\textendash}carbohydrate stacking.",

author = "Manuela Tosin and Helge M{\"u}ller-Bunz and Murphy, \{Paul V.\}",

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AU - Tosin, Manuela

AU - Müller-Bunz, Helge

AU - Murphy, Paul V.

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N2 - The crystal structure of a bivalent glycocluster containing aromatic amides reveals that alkylation of secondary amides alters amide configuration and thus carbohydrate presentation. This also facilitates non covalent interactions (azide–azide, carbonyl–pyranose and aromatic–pyranose) and thus carbohydrate–carbohydrate stacking.

AB - The crystal structure of a bivalent glycocluster containing aromatic amides reveals that alkylation of secondary amides alters amide configuration and thus carbohydrate presentation. This also facilitates non covalent interactions (azide–azide, carbonyl–pyranose and aromatic–pyranose) and thus carbohydrate–carbohydrate stacking.

UR - https://www.scopus.com/pages/publications/1642368169

U2 - 10.1039/b313934d

DO - 10.1039/b313934d

M3 - Article

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VL - 4

SP - 494

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JO - Chemical Communications

JF - Chemical Communications

IS - 5

ER -

Synthesis and X-ray single crystal structure of a bivalent glycocluster

Abstract

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