Study of the microstructure evolution of heat treated Ti-rich NiTi shape memory alloy

Martensitic evolution in Ti-rich NiTi alloy, Ti50.5Ni49.5, has been investigated as a function of annealing, solution treatment and a combination thereof and a detailed electron microscopic investigation carried out. Self accommodated martensite plates resulted in all heat treated samples. Martensitic 011 type II twins, which are common in NiTi shape memory alloys, was found in both as-received and heat-treated samples. Solution treated samples, additionally, showed {11-1} type I twinning was also found in samples that have been annealed after solution-treatment. Another common feature of the microstructure in both as-received and heat treated samples is the formation of Ti2Ni precipitates. The size, number and dispersions of these precipitates can be controlled by resorting to a suitable heat treatment e.g. solution treatment. (C) 2015 Elsevier Inc. All rights reserved.Martensitic evolution in Ti-rich NiTi alloy, Ti50.5Ni49.5, has been investigated as a function of annealing, solution treatment and a combination thereof and a detailed electron microscopic investigation carried out. Self accommodated martensite plates resulted in all heat treated samples. Martensitic 011 type II twins, which are common in NiTi shape memory alloys, was found in both as-received and heat-treated samples. Solution treated samples, additionally, showed {11-1} type I twinning was also found in samples that have been annealed after solution-treatment. Another common feature of the microstructure in both as-received and heat treated samples is the formation of Ti2Ni precipitates. The size, number and dispersions of these precipitates can be controlled by resorting to a suitable heat treatment e.g. solution treatment. (C) 2015 Elsevier Inc. All rights reserved.