Studies in the preparation of novel P-chirogenic binaphthyl monophosphanes (MOPs)

Nessan J. Kerrigan; Eoin C. Dunne; Desmond Cunningham; Patrick McArdle; Karen Gilligan; Declan G. Gilheany

doi:10.1016/j.tetlet.2003.09.109

Studies in the preparation of novel P-chirogenic binaphthyl monophosphanes (MOPs)

Nessan J. Kerrigan, Eoin C. Dunne, Desmond Cunningham, Patrick McArdle, Karen Gilligan, Declan G. Gilheany

Research output: Contribution to a Journal (Peer & Non Peer) › Article › peer-review

28 Citations (Scopus)

Abstract

Several routes to P-chirogenic binaphthyl monophosphanes (MOPs) and their derivatives were investigated. Palladium catalysed coupling gave access to a new class of P-chirogenic phosphane oxides from which the phosphane can be obtained by reduction. Substituents on phosphorus strongly influence the efficiency of the P-C coupling reaction, which is only slightly stereoselective.

Original language	English
Pages (from-to)	8461-8465
Number of pages	5
Journal	Tetrahedron Letters
Volume	44
Issue number	46
DOIs	https://doi.org/10.1016/j.tetlet.2003.09.109
Publication status	Published - 10 Nov 2003
Externally published	Yes

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10.1016/j.tetlet.2003.09.109

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title = "Studies in the preparation of novel P-chirogenic binaphthyl monophosphanes (MOPs)",

abstract = "Several routes to P-chirogenic binaphthyl monophosphanes (MOPs) and their derivatives were investigated. Palladium catalysed coupling gave access to a new class of P-chirogenic phosphane oxides from which the phosphane can be obtained by reduction. Substituents on phosphorus strongly influence the efficiency of the P-C coupling reaction, which is only slightly stereoselective.",

author = "Kerrigan, \{Nessan J.\} and Dunne, \{Eoin C.\} and Desmond Cunningham and Patrick McArdle and Karen Gilligan and Gilheany, \{Declan G.\}",

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AU - Kerrigan, Nessan J.

AU - Dunne, Eoin C.

AU - Cunningham, Desmond

AU - McArdle, Patrick

AU - Gilligan, Karen

AU - Gilheany, Declan G.

PY - 2003/11/10

Y1 - 2003/11/10

N2 - Several routes to P-chirogenic binaphthyl monophosphanes (MOPs) and their derivatives were investigated. Palladium catalysed coupling gave access to a new class of P-chirogenic phosphane oxides from which the phosphane can be obtained by reduction. Substituents on phosphorus strongly influence the efficiency of the P-C coupling reaction, which is only slightly stereoselective.

AB - Several routes to P-chirogenic binaphthyl monophosphanes (MOPs) and their derivatives were investigated. Palladium catalysed coupling gave access to a new class of P-chirogenic phosphane oxides from which the phosphane can be obtained by reduction. Substituents on phosphorus strongly influence the efficiency of the P-C coupling reaction, which is only slightly stereoselective.

UR - https://www.scopus.com/pages/publications/0141922082

U2 - 10.1016/j.tetlet.2003.09.109

DO - 10.1016/j.tetlet.2003.09.109

M3 - Article

SN - 0040-4039

VL - 44

SP - 8461

EP - 8465

JO - Tetrahedron Letters

JF - Tetrahedron Letters

IS - 46

ER -

Studies in the preparation of novel P-chirogenic binaphthyl monophosphanes (MOPs)

Abstract

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