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Stereospecific synthesis of beta-D-allopyrano sides by dihydroxylation of beta-D-erythro-2,3-dideoxyhex-2-enopyranosides

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Abstract

The synthesis of 4,6-O-benzylidene-beta -D-erythro-2-3-dideoxyhex-2-enopyranosides and their osmium and ruthenium catalysed dihydroxylation reactions have been investigated. These reactions have been shown, for a range of monosaccharides and a disaccharide, to proceed stereospecifically to give beta -D-allopyranosides in moderate to excellent yield. (C) 2001 Published by Elsevier Science Ltd.
Original languageEnglish (Ireland)
Number of pages9
JournalCarbohydrate Research
Volume334
Publication statusPublished - 1 Sep 2001

Authors (Note for portal: view the doc link for the full list of authors)

  • Authors
  • Murphy, PV,O'Brien, JL,Smith, AB

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