Stereochemical Study of Puna'auic Acid, an Allenic Fatty Acid from the Eastern Indo-Pacific Cyanobacterium Pseudanabaena sp

Emmanuel Roulland; Hiren Solanki; Kevin Calabro; Mayalen Zubia; Grégory Genta-Jouve; Olivier P. Thomas

doi:10.1021/acs.orglett.8b00654

Stereochemical Study of Puna'auic Acid, an Allenic Fatty Acid from the Eastern Indo-Pacific Cyanobacterium Pseudanabaena sp

Emmanuel Roulland
, Hiren Solanki
, Kevin Calabro
, Mayalen Zubia
, Grégory Genta-Jouve
, Olivier P. Thomas

Sustainable World

Université Paris Descartes
University of Galway
University of French Polynesia

Research output: Contribution to a Journal (Peer & Non Peer) › Article › peer-review

17 Citations (Scopus)

Abstract

The isolation and structure elucidation of puna'auic acid, an allenic fatty acid isolated from a marine cyanobacterium, is described. All configurations were first assessed through molecular modeling of NMR and ECD spectra and then confirmed through a straightforward enantioselective total synthesis of puna'auic acid featuring a key reductive opening of a propargylic epoxide.

Original language	English
Pages (from-to)	2311-2314
Number of pages	4
Journal	Organic Letters
Volume	20
Issue number	8
DOIs	https://doi.org/10.1021/acs.orglett.8b00654
Publication status	Published - 20 Apr 2018

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10.1021/acs.orglett.8b00654

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abstract = "The isolation and structure elucidation of puna'auic acid, an allenic fatty acid isolated from a marine cyanobacterium, is described. All configurations were first assessed through molecular modeling of NMR and ECD spectra and then confirmed through a straightforward enantioselective total synthesis of puna'auic acid featuring a key reductive opening of a propargylic epoxide.",

author = "Emmanuel Roulland and Hiren Solanki and Kevin Calabro and Mayalen Zubia and Gr{\'e}gory Genta-Jouve and Thomas, \{Olivier P.\}",

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AU - Roulland, Emmanuel

AU - Solanki, Hiren

AU - Calabro, Kevin

AU - Zubia, Mayalen

AU - Genta-Jouve, Grégory

AU - Thomas, Olivier P.

PY - 2018/4/20

Y1 - 2018/4/20

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AB - The isolation and structure elucidation of puna'auic acid, an allenic fatty acid isolated from a marine cyanobacterium, is described. All configurations were first assessed through molecular modeling of NMR and ECD spectra and then confirmed through a straightforward enantioselective total synthesis of puna'auic acid featuring a key reductive opening of a propargylic epoxide.

UR - https://www.scopus.com/pages/publications/85045917458

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DO - 10.1021/acs.orglett.8b00654

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AN - SCOPUS:85045917458

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JO - Organic Letters

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ER -

Stereochemical Study of Puna'auic Acid, an Allenic Fatty Acid from the Eastern Indo-Pacific Cyanobacterium Pseudanabaena sp

Abstract

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