Abstract
A regional climate model is used to evaluate dry deposition of ozone over the North East Atlantic. Results are presented for a deposition scheme accounting for turbulent and chemical enhancement of oceanic ozone deposition and a second non-chemical, parameterised gaseous dry deposition scheme. The first deposition scheme was constrained to account for sea-surface ozone-iodide reactions and the sensitivity of modelled ozone concentrations to oceanic iodide concentration was investigated. Simulations were also performed using nominal reaction rate derived from in-situ ozone deposition measurements and using a preliminary representation of organic chemistry. Results show insensitivity of ambient ozone concentrations modelled by the chemical-enhanced scheme to oceanic iodide concentrations, and iodide reactions alone cannot account for observed deposition velocities. Consequently, we suggest a missing chemical sink due to reactions of ozone with organic matter at the air-sea interface. Ozone loss rates are estimated to be in the range of 0.5-6 ppb per day. A potentially significant ozone-driven flux of iodine to the atmosphere is estimated to be in the range of 2.5-500M molec cm(-2) s(-1), leading to amixing-layer enhancement of organo-iodine concentrations of 0.1-22.0 ppt, with an average increase in the N.E. Atlantic of around 4 ppt per day.
| Original language | English (Ireland) |
|---|---|
| Journal | Adv Meteorol |
| Publication status | Published - 1 Jan 2010 |
Authors (Note for portal: view the doc link for the full list of authors)
- Authors
- Coleman, L,Varghese, S,Tripathi, OP,Jennings, SG,O'Dowd, CD