Oxidative activation of CoII in Schiff base complexes in the presence of n-butyltin trichloride: The molecular structure of BunSn(OMe)Cl2·CoCl(salen) [salen = N,N’- ethylenebis(salicylideneaminato)]

Desmond Cunningham; Tim Higgins; Brendan Kneafsey; Patrick McArdle; John Simmie

doi:10.1039/C39850000231

Oxidative activation of Co^II in Schiff base complexes in the presence of n-butyltin trichloride: The molecular structure of BuⁿSn(OMe)Cl₂·CoCl(salen) [salen = N,N’- ethylenebis(salicylideneaminato)]

Desmond Cunningham
, Tim Higgins
, Brendan Kneafsey
, Patrick McArdle
, John Simmie

Cellular & Molecular Medicine

Research output: Contribution to a Journal (Peer & Non Peer) › Article › peer-review

21 Citations (Scopus)

Abstract

Air stable chloroform solutions of Schiff base complexes of Coⁱⁱ undergo rapid cobalt oxidation on addition of n-butyltin trichloride yielding complexes in which, as exemplified by the crystal structure of BuⁿSn(OMe)Cl₂·CoCl-(salen) [salen = N,N’-ethylenebis(salicylideneaminato)], the cobalt(iii) Schiff base species behave as Lewis bases towards tin(iv).

Original language	English
Pages (from-to)	231-232
Number of pages	2
Journal	Journal of the Chemical Society D: Chemical Communications
Issue number	4
DOIs	https://doi.org/10.1039/C39850000231
Publication status	Published - 1985

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Cunningham, D., Higgins, T., Kneafsey, B., McArdle, P., & Simmie, J. (1985). Oxidative activation of Co^II in Schiff base complexes in the presence of n-butyltin trichloride: The molecular structure of BuⁿSn(OMe)Cl₂·CoCl(salen) [salen = N,N’- ethylenebis(salicylideneaminato)]. Journal of the Chemical Society D: Chemical Communications, (4), 231-232. https://doi.org/10.1039/C39850000231

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title = "Oxidative activation of CoII in Schiff base complexes in the presence of n-butyltin trichloride: The molecular structure of BunSn(OMe)Cl2·CoCl(salen) [salen = N,N{\textquoteright}- ethylenebis(salicylideneaminato)]",

abstract = "Air stable chloroform solutions of Schiff base complexes of Coii undergo rapid cobalt oxidation on addition of n-butyltin trichloride yielding complexes in which, as exemplified by the crystal structure of BunSn(OMe)Cl2·CoCl-(salen) [salen = N,N{\textquoteright}-ethylenebis(salicylideneaminato)], the cobalt(iii) Schiff base species behave as Lewis bases towards tin(iv).",

author = "Desmond Cunningham and Tim Higgins and Brendan Kneafsey and Patrick McArdle and John Simmie",

year = "1985",

doi = "10.1039/C39850000231",

language = "English",

pages = "231--232",

journal = "Journal of the Chemical Society D: Chemical Communications",

issn = "0022-4936",

number = "4",

}

Cunningham, D, Higgins, T, Kneafsey, B, McArdle, P & Simmie, J 1985, 'Oxidative activation of Co^II in Schiff base complexes in the presence of n-butyltin trichloride: The molecular structure of BuⁿSn(OMe)Cl₂·CoCl(salen) [salen = N,N’- ethylenebis(salicylideneaminato)]', Journal of the Chemical Society D: Chemical Communications, no. 4, pp. 231-232. https://doi.org/10.1039/C39850000231

Oxidative activation of Co^II in Schiff base complexes in the presence of n-butyltin trichloride: The molecular structure of BuⁿSn(OMe)Cl₂·CoCl(salen) [salen = N,N’- ethylenebis(salicylideneaminato)]. / Cunningham, Desmond; Higgins, Tim; Kneafsey, Brendan et al.
In: Journal of the Chemical Society D: Chemical Communications, No. 4, 1985, p. 231-232.

Research output: Contribution to a Journal (Peer & Non Peer) › Article › peer-review

TY - JOUR

T1 - Oxidative activation of CoII in Schiff base complexes in the presence of n-butyltin trichloride

T2 - The molecular structure of BunSn(OMe)Cl2·CoCl(salen) [salen = N,N’- ethylenebis(salicylideneaminato)]

AU - Cunningham, Desmond

AU - Higgins, Tim

AU - Kneafsey, Brendan

AU - McArdle, Patrick

AU - Simmie, John

PY - 1985

Y1 - 1985

N2 - Air stable chloroform solutions of Schiff base complexes of Coii undergo rapid cobalt oxidation on addition of n-butyltin trichloride yielding complexes in which, as exemplified by the crystal structure of BunSn(OMe)Cl2·CoCl-(salen) [salen = N,N’-ethylenebis(salicylideneaminato)], the cobalt(iii) Schiff base species behave as Lewis bases towards tin(iv).

AB - Air stable chloroform solutions of Schiff base complexes of Coii undergo rapid cobalt oxidation on addition of n-butyltin trichloride yielding complexes in which, as exemplified by the crystal structure of BunSn(OMe)Cl2·CoCl-(salen) [salen = N,N’-ethylenebis(salicylideneaminato)], the cobalt(iii) Schiff base species behave as Lewis bases towards tin(iv).

UR - https://www.scopus.com/pages/publications/37049104438

U2 - 10.1039/C39850000231

DO - 10.1039/C39850000231

M3 - Article

AN - SCOPUS:37049104438

SN - 0022-4936

SP - 231

EP - 232

JO - Journal of the Chemical Society D: Chemical Communications

JF - Journal of the Chemical Society D: Chemical Communications

IS - 4

ER -

Oxidative activation of Co^II in Schiff base complexes in the presence of n-butyltin trichloride: The molecular structure of BuⁿSn(OMe)Cl₂·CoCl(salen) [salen = N,N’- ethylenebis(salicylideneaminato)]

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