NUCLEATION AND ATMOSPHERIC AEROSOLS

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Abstract

High-time resolution measurements of primary marine organic sea spray physico-chemical properties reveal submicron organic marine aerosol plume concentrations peaking at 3.8 mu g m-3, moreover, it shows an apparent dichotomous behavior of marine organics in terms of water uptake: specifically sea-spray aerosol enriched in organic matter possesses a low Hydroscopic Growth Factor (HGF similar to 1.25) while simultaneously having a cloud condensation nucleus condensation nuclei (CCN CN) activation efficiency of between 83% at 0.25% supersaturation and 100% at 0.75%. Simultaneous retrieval of Cloud Droplet Number Concentration (CDNC) during primary organic aerosol plumes reveals CDNC concentrations of 350 cm(-3) for organic mass concentrations 3-4 mu g m(-3). It is demonstrated that the retrieved high CDNCs under clean marine conditions can only be explained by organic sea-spray and corroborates the high CCN activation efficiency associated with primary organics. It is postulated that marine hydrogels are responsible for this dichotomous behavior
Original languageEnglish (Ireland)
Title of host publicationA Dual Behavior of Primary Marine Organics
Number of pages4
Volume1527
DOIs
Publication statusPublished - 1 Jan 2013

Authors (Note for portal: view the doc link for the full list of authors)

  • Authors
  • Ovadnevaite, J,Ceburnis, D,Martucci, G,Bialek, J,Monahan, C,Rinaldi, M,Facchini, MC,O'Dowd, C

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