NOVEL BONDING OF TERTIARY DIPHOSPHINES TO METAL RING CARBONYL-COMPLEXES

Patrick Mcardle

Research output: Contribution to a Journal (Peer & Non Peer)Articlepeer-review

Abstract

Tertiary diphosphines form complexes with various metal ring carbonyl cations of new and novel structural types including ring adducts, e.g. [(eta-4-C7H9-5-exo-eta-1-PPh2CH2PPh2)Fe(CO)3]BF4 diphosphine bridged ring dimers, e.g. Ph2P(CH2)2PPh2[(eta-4-C7H9)Fe(CO)3]2[BF4]2 and diphosphine bridged ring-metal dimers, e.g. [(eta-5-C5H5)Fe(CO)2PPh2(CH2)3PPh2(exo-eta-6-C7H7)Cr(CO)3][BF4]2.
Original languageEnglish (Ireland)
Number of pages2
JournalJournal Of The Chemical Society-Chemical Communications
Publication statusPublished - 1 May 1992

Authors (Note for portal: view the doc link for the full list of authors)

  • Authors
  • BROWN, DA,BURNS, J,ELGAMATI, I,GLASS, WK,KREDDAN, K,SALAMA, M,CUNNINGHAM, D,HIGGINS, T,MCARDLE, P

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