Novel bonding of tertiary diphosphines to metal ring carbonyl complexes

David A. Brown; John Burns; Ibrahim El-Gamati; William K. Glass; Khaled Kreddan; Mabrouk Salama; Desmond Cunningham; Tim Higgins; Patrick McArdle

doi:10.1039/C39920000701

Novel bonding of tertiary diphosphines to metal ring carbonyl complexes

David A. Brown, John Burns, Ibrahim El-Gamati, William K. Glass, Khaled Kreddan, Mabrouk Salama, Desmond Cunningham, Tim Higgins, Patrick McArdle

Research output: Contribution to a Journal (Peer & Non Peer) › Article › peer-review

4 Citations (Scopus)

Abstract

Tertiary diphosphines form complexes with various metal ring carbonyl cations of new and novel structural types including ring adducts, e.g. [(η⁴-C₇H₉-5-exo-η¹-PPh ₂CH₂PPh₂)Fe(CO)₃]BF₄ diphosphine bridged ring dimers, e.g. Ph₂P(CH₂) ₂PPh₂[(η⁴-C₇H ₉)Fe(CO)₃]₂[BF₄]₂ and diphosphine bridged ring-metal dimers, e.g.. [(η⁵-C ₅H₅)Fe(CO)₂PPh₂(CH₂) ₃PPh₂(exo-η⁶-C₇H ₇)Cr(CO)₃][BF₄]₂.

Original language	English
Pages (from-to)	701-702
Number of pages	2
Journal	Journal of the Chemical Society D: Chemical Communications
Issue number	9
DOIs	https://doi.org/10.1039/C39920000701
Publication status	Published - 1992
Externally published	Yes

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title = "Novel bonding of tertiary diphosphines to metal ring carbonyl complexes",

abstract = "Tertiary diphosphines form complexes with various metal ring carbonyl cations of new and novel structural types including ring adducts, e.g. [(η4-C7H9-5-exo-η1-PPh 2CH2PPh2)Fe(CO)3]BF4 diphosphine bridged ring dimers, e.g. Ph2P(CH2) 2PPh2[(η4-C7H 9)Fe(CO)3]2[BF4]2 and diphosphine bridged ring-metal dimers, e.g.. [(η5-C 5H5)Fe(CO)2PPh2(CH2) 3PPh2(exo-η6-C7H 7)Cr(CO)3][BF4]2.",

author = "Brown, {David A.} and John Burns and Ibrahim El-Gamati and Glass, {William K.} and Khaled Kreddan and Mabrouk Salama and Desmond Cunningham and Tim Higgins and Patrick McArdle",

year = "1992",

doi = "10.1039/C39920000701",

language = "English",

pages = "701--702",

journal = "Journal of the Chemical Society D: Chemical Communications",

issn = "0022-4936",

number = "9",

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TY - JOUR

T1 - Novel bonding of tertiary diphosphines to metal ring carbonyl complexes

AU - Brown, David A.

AU - Burns, John

AU - El-Gamati, Ibrahim

AU - Glass, William K.

AU - Kreddan, Khaled

AU - Salama, Mabrouk

AU - Cunningham, Desmond

AU - Higgins, Tim

AU - McArdle, Patrick

PY - 1992

Y1 - 1992

N2 - Tertiary diphosphines form complexes with various metal ring carbonyl cations of new and novel structural types including ring adducts, e.g. [(η4-C7H9-5-exo-η1-PPh 2CH2PPh2)Fe(CO)3]BF4 diphosphine bridged ring dimers, e.g. Ph2P(CH2) 2PPh2[(η4-C7H 9)Fe(CO)3]2[BF4]2 and diphosphine bridged ring-metal dimers, e.g.. [(η5-C 5H5)Fe(CO)2PPh2(CH2) 3PPh2(exo-η6-C7H 7)Cr(CO)3][BF4]2.

AB - Tertiary diphosphines form complexes with various metal ring carbonyl cations of new and novel structural types including ring adducts, e.g. [(η4-C7H9-5-exo-η1-PPh 2CH2PPh2)Fe(CO)3]BF4 diphosphine bridged ring dimers, e.g. Ph2P(CH2) 2PPh2[(η4-C7H 9)Fe(CO)3]2[BF4]2 and diphosphine bridged ring-metal dimers, e.g.. [(η5-C 5H5)Fe(CO)2PPh2(CH2) 3PPh2(exo-η6-C7H 7)Cr(CO)3][BF4]2.

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U2 - 10.1039/C39920000701

DO - 10.1039/C39920000701

M3 - Article

SN - 0022-4936

SP - 701

EP - 702

JO - Journal of the Chemical Society D: Chemical Communications

JF - Journal of the Chemical Society D: Chemical Communications

IS - 9

ER -

Novel bonding of tertiary diphosphines to metal ring carbonyl complexes

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