New chiral diamide ligands: synthesis and application in allylic alkylation: synthesis and application in allylic alkylation

Patrick O'Leary

doi:10.1016/j.tetasy.2008.01.018

New chiral diamide ligands: synthesis and application in allylic alkylation: synthesis and application in allylic alkylation

Patrick O'Leary

Physics

University of Galway

Research output: Contribution to a Journal (Peer & Non Peer) › Article › peer-review

19 Citations (Scopus)

Abstract

A new family of chiral diamide ligands has been designed and synthesised. These ligands have been successfully applied to an asymmetric allylic substitution reaction. A palladium complex of one of the diamide ligands achieved enantio selectivities of up to 93% in the allylic alkylation of 1,3-diphenyl-3-acetoxyprop-1-ene. (C) 2008 Elsevier Ltd. All rights reserved.

Original language	English (Ireland)
Pages (from-to)	391-396
Number of pages	6
Journal	TETRAHEDRON-ASYMMETRY
Volume	19
Issue number	3
DOIs	https://doi.org/10.1016/j.tetasy.2008.01.018
Publication status	Published - 1 Feb 2008

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Authors
Bateman, L,Breeden, SW,O'Leary, P

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10.1016/j.tetasy.2008.01.018

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abstract = "A new family of chiral diamide ligands has been designed and synthesised. These ligands have been successfully applied to an asymmetric allylic substitution reaction. A palladium complex of one of the diamide ligands achieved enantio selectivities of up to 93\% in the allylic alkylation of 1,3-diphenyl-3-acetoxyprop-1-ene. (C) 2008 Elsevier Ltd. All rights reserved.",

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N2 - A new family of chiral diamide ligands has been designed and synthesised. These ligands have been successfully applied to an asymmetric allylic substitution reaction. A palladium complex of one of the diamide ligands achieved enantio selectivities of up to 93% in the allylic alkylation of 1,3-diphenyl-3-acetoxyprop-1-ene. (C) 2008 Elsevier Ltd. All rights reserved.

AB - A new family of chiral diamide ligands has been designed and synthesised. These ligands have been successfully applied to an asymmetric allylic substitution reaction. A palladium complex of one of the diamide ligands achieved enantio selectivities of up to 93% in the allylic alkylation of 1,3-diphenyl-3-acetoxyprop-1-ene. (C) 2008 Elsevier Ltd. All rights reserved.

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DO - 10.1016/j.tetasy.2008.01.018

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New chiral diamide ligands: synthesis and application in allylic alkylation: synthesis and application in allylic alkylation

Abstract

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