Measurement of association constants in metal orotate complexes by 1H NMR spectroscopy: the metal substituent effect on triple hydrogen bonding ability

Xingling Xu; Michael Hynes; Stuart L. James; D. Michael P. Mingos

doi:10.1080/10587250008038239

Measurement of association constants in metal orotate complexes by ¹H NMR spectroscopy: the metal substituent effect on triple hydrogen bonding ability

Xingling Xu, Michael Hynes, Stuart L. James, D. Michael P. Mingos

Research output: Contribution to a Journal (Peer & Non Peer) › Conference article › peer-review

1 Citation (Scopus)

Abstract

The metal substituent effect on complementary triple hydrogen bonding pairs was investigated by ¹H NMR spectroscopy. The results demonstrated that the metal ion reduced the hydrogen bonding ability of the ADA complex [NBu₄][Rh(cod)(orotate)] with 2,6-diaminopyridine.

Original language	English
Pages (from-to)	15-27
Number of pages	13
Journal	Molecular Crystals and Liquid Crystals Science and Technology Section A: Molecular Crystals and Liquid Crystals
Volume	342
DOIs	https://doi.org/10.1080/10587250008038239
Publication status	Published - 2000
Event	Proceedings of the International Symposium Molecular Design and Funtionalities of Assambled Metal Complexes (AMS'99) - Kyoto, Jpn Duration: 30 Nov 1999 → 2 Dec 1999

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10.1080/10587250008038239

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Xu, X., Hynes, M., James, S. L., & Mingos, D. M. P. (2000). Measurement of association constants in metal orotate complexes by ¹H NMR spectroscopy: the metal substituent effect on triple hydrogen bonding ability. Molecular Crystals and Liquid Crystals Science and Technology Section A: Molecular Crystals and Liquid Crystals, 342, 15-27. https://doi.org/10.1080/10587250008038239

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title = "Measurement of association constants in metal orotate complexes by 1H NMR spectroscopy: the metal substituent effect on triple hydrogen bonding ability",

abstract = "The metal substituent effect on complementary triple hydrogen bonding pairs was investigated by 1H NMR spectroscopy. The results demonstrated that the metal ion reduced the hydrogen bonding ability of the ADA complex [NBu4][Rh(cod)(orotate)] with 2,6-diaminopyridine.",

author = "Xingling Xu and Michael Hynes and James, {Stuart L.} and Mingos, {D. Michael P.}",

year = "2000",

doi = "10.1080/10587250008038239",

language = "English",

volume = "342",

pages = "15--27",

journal = "Molecular Crystals and Liquid Crystals Science and Technology Section A: Molecular Crystals and Liquid Crystals",

issn = "1058-725X",

note = "Proceedings of the International Symposium Molecular Design and Funtionalities of Assambled Metal Complexes (AMS'99) ; Conference date: 30-11-1999 Through 02-12-1999",

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Xu, X, Hynes, M, James, SL & Mingos, DMP 2000, 'Measurement of association constants in metal orotate complexes by ¹H NMR spectroscopy: the metal substituent effect on triple hydrogen bonding ability', Molecular Crystals and Liquid Crystals Science and Technology Section A: Molecular Crystals and Liquid Crystals, vol. 342, pp. 15-27. https://doi.org/10.1080/10587250008038239

Measurement of association constants in metal orotate complexes by ¹H NMR spectroscopy: the metal substituent effect on triple hydrogen bonding ability. / Xu, Xingling; Hynes, Michael; James, Stuart L. et al.
In: Molecular Crystals and Liquid Crystals Science and Technology Section A: Molecular Crystals and Liquid Crystals, Vol. 342, 2000, p. 15-27.

Research output: Contribution to a Journal (Peer & Non Peer) › Conference article › peer-review

TY - JOUR

T1 - Measurement of association constants in metal orotate complexes by 1H NMR spectroscopy

T2 - Proceedings of the International Symposium Molecular Design and Funtionalities of Assambled Metal Complexes (AMS'99)

AU - Xu, Xingling

AU - Hynes, Michael

AU - James, Stuart L.

AU - Mingos, D. Michael P.

PY - 2000

Y1 - 2000

N2 - The metal substituent effect on complementary triple hydrogen bonding pairs was investigated by 1H NMR spectroscopy. The results demonstrated that the metal ion reduced the hydrogen bonding ability of the ADA complex [NBu4][Rh(cod)(orotate)] with 2,6-diaminopyridine.

AB - The metal substituent effect on complementary triple hydrogen bonding pairs was investigated by 1H NMR spectroscopy. The results demonstrated that the metal ion reduced the hydrogen bonding ability of the ADA complex [NBu4][Rh(cod)(orotate)] with 2,6-diaminopyridine.

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U2 - 10.1080/10587250008038239

DO - 10.1080/10587250008038239

M3 - Conference article

AN - SCOPUS:0033646181

SN - 1058-725X

VL - 342

SP - 15

EP - 27

JO - Molecular Crystals and Liquid Crystals Science and Technology Section A: Molecular Crystals and Liquid Crystals

JF - Molecular Crystals and Liquid Crystals Science and Technology Section A: Molecular Crystals and Liquid Crystals

Y2 - 30 November 1999 through 2 December 1999

ER -

Measurement of association constants in metal orotate complexes by ¹H NMR spectroscopy: the metal substituent effect on triple hydrogen bonding ability

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