Ligand substitution at five-co-ordinate centres: Associate mechanism for the high-spin complex 2,9-dimethyl-1,10-phenanthrolinebis-(OO′-dimethyl dithiophosphato)nickel(II)

Michael J. Hynes; Patricia F. Brannick

doi:10.1039/C39770000942

Ligand substitution at five-co-ordinate centres: Associate mechanism for the high-spin complex 2,9-dimethyl-1,10-phenanthrolinebis-(OO′-dimethyl dithiophosphato)nickel(II)

Michael J. Hynes, Patricia F. Brannick

University of Galway

Research output: Contribution to a Journal (Peer & Non Peer) › Article › peer-review

5 Citations (Scopus)

Abstract

The reaction between bis(OO′-dimethyl dithiophosphato)nickel(II) and 2,9-dimethyl-1,10-phenanthroline giving a high-spin five-co-ordinate adduct has been investigated; the adduct reacts with 2,2′-bipyridyl and 1,10-phenanthroline by an almost exclusively associative mechanism.

Original language	English
Pages (from-to)	942-944
Number of pages	3
Journal	Journal of the Chemical Society D: Chemical Communications
Issue number	24
DOIs	https://doi.org/10.1039/C39770000942
Publication status	Published - 1977

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title = "Ligand substitution at five-co-ordinate centres: Associate mechanism for the high-spin complex 2,9-dimethyl-1,10-phenanthrolinebis-(OO′-dimethyl dithiophosphato)nickel(II)",

abstract = "The reaction between bis(OO′-dimethyl dithiophosphato)nickel(II) and 2,9-dimethyl-1,10-phenanthroline giving a high-spin five-co-ordinate adduct has been investigated; the adduct reacts with 2,2′-bipyridyl and 1,10-phenanthroline by an almost exclusively associative mechanism.",

author = "Hynes, \{Michael J.\} and Brannick, \{Patricia F.\}",

year = "1977",

doi = "10.1039/C39770000942",

language = "English",

pages = "942--944",

journal = "Journal of the Chemical Society D: Chemical Communications",

issn = "0022-4936",

number = "24",

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Ligand substitution at five-co-ordinate centres: Associate mechanism for the high-spin complex 2,9-dimethyl-1,10-phenanthrolinebis-(OO′-dimethyl dithiophosphato)nickel(II). / Hynes, Michael J.; Brannick, Patricia F.
In: Journal of the Chemical Society D: Chemical Communications, No. 24, 1977, p. 942-944.

Research output: Contribution to a Journal (Peer & Non Peer) › Article › peer-review

TY - JOUR

T1 - Ligand substitution at five-co-ordinate centres

T2 - Associate mechanism for the high-spin complex 2,9-dimethyl-1,10-phenanthrolinebis-(OO′-dimethyl dithiophosphato)nickel(II)

AU - Hynes, Michael J.

AU - Brannick, Patricia F.

PY - 1977

Y1 - 1977

N2 - The reaction between bis(OO′-dimethyl dithiophosphato)nickel(II) and 2,9-dimethyl-1,10-phenanthroline giving a high-spin five-co-ordinate adduct has been investigated; the adduct reacts with 2,2′-bipyridyl and 1,10-phenanthroline by an almost exclusively associative mechanism.

AB - The reaction between bis(OO′-dimethyl dithiophosphato)nickel(II) and 2,9-dimethyl-1,10-phenanthroline giving a high-spin five-co-ordinate adduct has been investigated; the adduct reacts with 2,2′-bipyridyl and 1,10-phenanthroline by an almost exclusively associative mechanism.

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DO - 10.1039/C39770000942

M3 - Article

SN - 0022-4936

SP - 942

EP - 944

JO - Journal of the Chemical Society D: Chemical Communications

JF - Journal of the Chemical Society D: Chemical Communications

IS - 24

ER -

Ligand substitution at five-co-ordinate centres: Associate mechanism for the high-spin complex 2,9-dimethyl-1,10-phenanthrolinebis-(OO′-dimethyl dithiophosphato)nickel(II)

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