Kinetics of the dehydrofluorination of vinyl fluoride in a single-pulse shock tube

J. M. Simmie; W. J. Quiring; E. Tschuikow-Roux

doi:10.1021/j100700a005

Kinetics of the dehydrofluorination of vinyl fluoride in a single-pulse shock tube

J. M. Simmie, W. J. Quiring, E. Tschuikow-Roux

Research output: Contribution to a Journal (Peer & Non Peer) › Article › peer-review

35 Citations (Scopus)

Abstract

The gas phase decomposition of vinyl fluoride has been studied in a single-pulse shock tube between about 1170 and 1350°K at total reflected shock pressures from 2800 to 3600 Torr. It is shown that vinyl fluoride decomposes by molecular elimination of hydrogen fluoride, CH₂ = CFH →^k C₂H₂ + HF. The first-order rate constant is given by k = 10^14.0±0.7 exp[-(70,800 ± 3600)/RT] sec^-1.

Original language	English
Pages (from-to)	992-994
Number of pages	3
Journal	Journal of Physical Chemistry
Volume	74
Issue number	5
DOIs	https://doi.org/10.1021/j100700a005
Publication status	Published - 1970
Externally published	Yes

Access to Document

10.1021/j100700a005

Cite this

@article{de99f476dad24f73aa68f7e1a3573f4c,

title = "Kinetics of the dehydrofluorination of vinyl fluoride in a single-pulse shock tube",

abstract = "The gas phase decomposition of vinyl fluoride has been studied in a single-pulse shock tube between about 1170 and 1350°K at total reflected shock pressures from 2800 to 3600 Torr. It is shown that vinyl fluoride decomposes by molecular elimination of hydrogen fluoride, CH2 = CFH →k C2H2 + HF. The first-order rate constant is given by k = 1014.0±0.7 exp[-(70,800 ± 3600)/RT] sec-1.",

author = "Simmie, {J. M.} and Quiring, {W. J.} and E. Tschuikow-Roux",

year = "1970",

doi = "10.1021/j100700a005",

language = "English",

volume = "74",

pages = "992--994",

journal = "Journal of Physical Chemistry",

issn = "0022-3654",

number = "5",

}

TY - JOUR

T1 - Kinetics of the dehydrofluorination of vinyl fluoride in a single-pulse shock tube

AU - Simmie, J. M.

AU - Quiring, W. J.

AU - Tschuikow-Roux, E.

PY - 1970

Y1 - 1970

N2 - The gas phase decomposition of vinyl fluoride has been studied in a single-pulse shock tube between about 1170 and 1350°K at total reflected shock pressures from 2800 to 3600 Torr. It is shown that vinyl fluoride decomposes by molecular elimination of hydrogen fluoride, CH2 = CFH →k C2H2 + HF. The first-order rate constant is given by k = 1014.0±0.7 exp[-(70,800 ± 3600)/RT] sec-1.

AB - The gas phase decomposition of vinyl fluoride has been studied in a single-pulse shock tube between about 1170 and 1350°K at total reflected shock pressures from 2800 to 3600 Torr. It is shown that vinyl fluoride decomposes by molecular elimination of hydrogen fluoride, CH2 = CFH →k C2H2 + HF. The first-order rate constant is given by k = 1014.0±0.7 exp[-(70,800 ± 3600)/RT] sec-1.

UR - http://www.scopus.com/inward/record.url?scp=0001351044&partnerID=8YFLogxK

U2 - 10.1021/j100700a005

DO - 10.1021/j100700a005

M3 - Article

SN - 0022-3654

VL - 74

SP - 992

EP - 994

JO - Journal of Physical Chemistry

JF - Journal of Physical Chemistry

IS - 5

ER -

Kinetics of the dehydrofluorination of vinyl fluoride in a single-pulse shock tube

Abstract

Access to Document

Other files and links

Fingerprint

Cite this