In search for mixed transition metal/lanthanide single-molecule magnets: Synthetic routes to NiII/TbIII and NiII/DyIII clusters featuring a 2-pyridyl oximate ligand

Constantina Papatriantafyllopoulou; Marta Estrader; Constantinos G. Efthymiou; Despina Dermitzaki; Konstantinos Gkotsis; Aris Terzis; Carmen Diaz; Spyros P. Perlepes

doi:10.1016/j.poly.2008.10.024

In search for mixed transition metal/lanthanide single-molecule magnets: Synthetic routes to Ni^II/Tb^III and Ni^II/Dy^III clusters featuring a 2-pyridyl oximate ligand

Constantina Papatriantafyllopoulou
, Marta Estrader
, Constantinos G. Efthymiou
, Despina Dermitzaki
, Konstantinos Gkotsis
, Aris Terzis
, Carmen Diaz
, Spyros P. Perlepes

Research output: Contribution to a Journal (Peer & Non Peer) › Article › peer-review

43 Citations (Scopus)

Abstract

Employing the mononuclear complex [Ni{(py)C(Me)NO}₂{(py)C(Me)NOH}] (1) as 'ligand' [(py)C(Me)NOH = methyl 2-pyridyl ketone oxime], the use of the 'metal complexes as ligands' approach has led to the synthesis of the mixed Ni^II/Ln^III complexes [NiTb{(py)C(Me)NO}₂(NO₃)₃{(py)C(Me)NOH} ] (2), [Ni₂Ln₂{(py)C(Me)NO}₆(NO₃) ₄] (Ln = Dy, 3; Ln = Tb, 4) and [Ni₂Tb{(py)C(Me)NO}₆](NO₃) (5). The structures of 2, 3, and 5, and the magnetic properties of 2 and 5 are briefly discussed.

Original language	English
Pages (from-to)	1652-1655
Number of pages	4
Journal	Polyhedron
Volume	28
Issue number	9-10
DOIs	https://doi.org/10.1016/j.poly.2008.10.024
Publication status	Published - 22 Jun 2009
Externally published	Yes

Keywords

'Metal complexes as ligands' strategy
2-Pyridyloximate ligands
Crystal structures
Heterometallic nickel-lanthanide complexes
Magnetic properties

Access to Document

10.1016/j.poly.2008.10.024

Cite this

Papatriantafyllopoulou, C., Estrader, M., Efthymiou, C. G., Dermitzaki, D., Gkotsis, K., Terzis, A., Diaz, C., & Perlepes, S. P. (2009). In search for mixed transition metal/lanthanide single-molecule magnets: Synthetic routes to Ni^II/Tb^III and Ni^II/Dy^III clusters featuring a 2-pyridyl oximate ligand. Polyhedron, 28(9-10), 1652-1655. https://doi.org/10.1016/j.poly.2008.10.024

@article{2d9c55b01da54c289eb820b1e7cfb534,

title = "In search for mixed transition metal/lanthanide single-molecule magnets: Synthetic routes to NiII/TbIII and NiII/DyIII clusters featuring a 2-pyridyl oximate ligand",

abstract = "Employing the mononuclear complex [Ni\{(py)C(Me)NO\}2\{(py)C(Me)NOH\}] (1) as 'ligand' [(py)C(Me)NOH = methyl 2-pyridyl ketone oxime], the use of the 'metal complexes as ligands' approach has led to the synthesis of the mixed NiII/LnIII complexes [NiTb\{(py)C(Me)NO\}2(NO3)3\{(py)C(Me)NOH\} ] (2), [Ni2Ln2\{(py)C(Me)NO\}6(NO3) 4] (Ln = Dy, 3; Ln = Tb, 4) and [Ni2Tb\{(py)C(Me)NO\}6](NO3) (5). The structures of 2, 3, and 5, and the magnetic properties of 2 and 5 are briefly discussed.",

keywords = "'Metal complexes as ligands' strategy, 2-Pyridyloximate ligands, Crystal structures, Heterometallic nickel-lanthanide complexes, Magnetic properties",

author = "Constantina Papatriantafyllopoulou and Marta Estrader and Efthymiou, \{Constantinos G.\} and Despina Dermitzaki and Konstantinos Gkotsis and Aris Terzis and Carmen Diaz and Perlepes, \{Spyros P.\}",

year = "2009",

month = jun,

day = "22",

doi = "10.1016/j.poly.2008.10.024",

language = "English",

volume = "28",

pages = "1652--1655",

journal = "Polyhedron",

issn = "0277-5387",

publisher = "Elsevier Ltd",

number = "9-10",

}

Papatriantafyllopoulou, C, Estrader, M, Efthymiou, CG, Dermitzaki, D, Gkotsis, K, Terzis, A, Diaz, C & Perlepes, SP 2009, 'In search for mixed transition metal/lanthanide single-molecule magnets: Synthetic routes to Ni^II/Tb^III and Ni^II/Dy^III clusters featuring a 2-pyridyl oximate ligand', Polyhedron, vol. 28, no. 9-10, pp. 1652-1655. https://doi.org/10.1016/j.poly.2008.10.024

In search for mixed transition metal/lanthanide single-molecule magnets: Synthetic routes to Ni^II/Tb^III and Ni^II/Dy^III clusters featuring a 2-pyridyl oximate ligand. / Papatriantafyllopoulou, Constantina; Estrader, Marta; Efthymiou, Constantinos G. et al.
In: Polyhedron, Vol. 28, No. 9-10, 22.06.2009, p. 1652-1655.

Research output: Contribution to a Journal (Peer & Non Peer) › Article › peer-review

TY - JOUR

T1 - In search for mixed transition metal/lanthanide single-molecule magnets

T2 - Synthetic routes to NiII/TbIII and NiII/DyIII clusters featuring a 2-pyridyl oximate ligand

AU - Papatriantafyllopoulou, Constantina

AU - Estrader, Marta

AU - Efthymiou, Constantinos G.

AU - Dermitzaki, Despina

AU - Gkotsis, Konstantinos

AU - Terzis, Aris

AU - Diaz, Carmen

AU - Perlepes, Spyros P.

PY - 2009/6/22

Y1 - 2009/6/22

N2 - Employing the mononuclear complex [Ni{(py)C(Me)NO}2{(py)C(Me)NOH}] (1) as 'ligand' [(py)C(Me)NOH = methyl 2-pyridyl ketone oxime], the use of the 'metal complexes as ligands' approach has led to the synthesis of the mixed NiII/LnIII complexes [NiTb{(py)C(Me)NO}2(NO3)3{(py)C(Me)NOH} ] (2), [Ni2Ln2{(py)C(Me)NO}6(NO3) 4] (Ln = Dy, 3; Ln = Tb, 4) and [Ni2Tb{(py)C(Me)NO}6](NO3) (5). The structures of 2, 3, and 5, and the magnetic properties of 2 and 5 are briefly discussed.

AB - Employing the mononuclear complex [Ni{(py)C(Me)NO}2{(py)C(Me)NOH}] (1) as 'ligand' [(py)C(Me)NOH = methyl 2-pyridyl ketone oxime], the use of the 'metal complexes as ligands' approach has led to the synthesis of the mixed NiII/LnIII complexes [NiTb{(py)C(Me)NO}2(NO3)3{(py)C(Me)NOH} ] (2), [Ni2Ln2{(py)C(Me)NO}6(NO3) 4] (Ln = Dy, 3; Ln = Tb, 4) and [Ni2Tb{(py)C(Me)NO}6](NO3) (5). The structures of 2, 3, and 5, and the magnetic properties of 2 and 5 are briefly discussed.

KW - 'Metal complexes as ligands' strategy

KW - 2-Pyridyloximate ligands

KW - Crystal structures

KW - Heterometallic nickel-lanthanide complexes

KW - Magnetic properties

UR - https://www.scopus.com/pages/publications/67349286819

U2 - 10.1016/j.poly.2008.10.024

DO - 10.1016/j.poly.2008.10.024

M3 - Article

SN - 0277-5387

VL - 28

SP - 1652

EP - 1655

JO - Polyhedron

JF - Polyhedron

IS - 9-10

ER -

In search for mixed transition metal/lanthanide single-molecule magnets: Synthetic routes to Ni^II/Tb^III and Ni^II/Dy^III clusters featuring a 2-pyridyl oximate ligand

Abstract

Keywords

Access to Document

Other files and links

Fingerprint

Cite this