High nuclearity structurally-related Mn supertetrahedral T4 aggregates

Katerina Skordi; Antonis Anastassiades; Adeline D. Fournet; Rahul Kumar; Michael Schulze; Wolfgang Wernsdorfer; George Christou; Vassilios Nastopoulos; Spyros P. Perlepes; Constantina Papatriantafyllopoulou; Anastasios J. Tasiopoulos

doi:10.1039/d1cc01815a

High nuclearity structurally-related Mn supertetrahedral T4 aggregates

Katerina Skordi
, Antonis Anastassiades
, Adeline D. Fournet
, Rahul Kumar
, Michael Schulze
, Wolfgang Wernsdorfer
, George Christou
, Vassilios Nastopoulos
, Spyros P. Perlepes
, Constantina Papatriantafyllopoulou
, Anastasios J. Tasiopoulos

Cellular & Molecular Medicine

University of Cyprus
University of Florida
Institute of Quantum Materials and Technologies (IQMT)
University of Patras

Research output: Contribution to a Journal (Peer & Non Peer) › Article › peer-review

7 Citations (Scopus)

Abstract

The simultaneous employment of 1,3-propanediol and di-2-pyridyl ketone in Mn carboxylate chemistry has provided access to three new, structurally-related [Mn24] and [Mn23] clusters. They are based on nanosized supertetrahedal T4 Mn/O structural cores and exhibit slow relaxation of magnetization below 3.5 K.

Original language	English
Pages (from-to)	12484-12487
Number of pages	4
Journal	Chemical Communications
Volume	57
Issue number	93
DOIs	https://doi.org/10.1039/d1cc01815a
Publication status	Published - 4 Dec 2021

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10.1039/d1cc01815a

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title = "High nuclearity structurally-related Mn supertetrahedral T4 aggregates",

abstract = "The simultaneous employment of 1,3-propanediol and di-2-pyridyl ketone in Mn carboxylate chemistry has provided access to three new, structurally-related [Mn24] and [Mn23] clusters. They are based on nanosized supertetrahedal T4 Mn/O structural cores and exhibit slow relaxation of magnetization below 3.5 K.",

author = "Katerina Skordi and Antonis Anastassiades and Fournet, \{Adeline D.\} and Rahul Kumar and Michael Schulze and Wolfgang Wernsdorfer and George Christou and Vassilios Nastopoulos and Perlepes, \{Spyros P.\} and Constantina Papatriantafyllopoulou and Tasiopoulos, \{Anastasios J.\}",

note = "Publisher Copyright: {\textcopyright} The Royal Society of Chemistry.",

year = "2021",

month = dec,

day = "4",

doi = "10.1039/d1cc01815a",

language = "English",

volume = "57",

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journal = "Chemical Communications",

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publisher = "Royal Society of Chemistry",

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TY - JOUR

T1 - High nuclearity structurally-related Mn supertetrahedral T4 aggregates

AU - Skordi, Katerina

AU - Anastassiades, Antonis

AU - Fournet, Adeline D.

AU - Kumar, Rahul

AU - Schulze, Michael

AU - Wernsdorfer, Wolfgang

AU - Christou, George

AU - Nastopoulos, Vassilios

AU - Perlepes, Spyros P.

AU - Papatriantafyllopoulou, Constantina

AU - Tasiopoulos, Anastasios J.

PY - 2021/12/4

Y1 - 2021/12/4

N2 - The simultaneous employment of 1,3-propanediol and di-2-pyridyl ketone in Mn carboxylate chemistry has provided access to three new, structurally-related [Mn24] and [Mn23] clusters. They are based on nanosized supertetrahedal T4 Mn/O structural cores and exhibit slow relaxation of magnetization below 3.5 K.

AB - The simultaneous employment of 1,3-propanediol and di-2-pyridyl ketone in Mn carboxylate chemistry has provided access to three new, structurally-related [Mn24] and [Mn23] clusters. They are based on nanosized supertetrahedal T4 Mn/O structural cores and exhibit slow relaxation of magnetization below 3.5 K.

UR - https://www.scopus.com/pages/publications/85120315469

U2 - 10.1039/d1cc01815a

DO - 10.1039/d1cc01815a

M3 - Article

SN - 1359-7345

VL - 57

SP - 12484

EP - 12487

JO - Chemical Communications

JF - Chemical Communications

IS - 93

ER -

High nuclearity structurally-related Mn supertetrahedral T4 aggregates

Abstract

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