High nuclearity structurally-related Mn supertetrahedral T4 aggregates

Katerina Skordi; Antonis Anastassiades; Adeline D. Fournet; Rahul Kumar; Michael Schulze; Wolfgang Wernsdorfer; George Christou; Vassilios Nastopoulos; Spyros P. Perlepes; Constantina Papatriantafyllopoulou; Anastasios J. Tasiopoulos

doi:10.1039/d1cc01815a

High nuclearity structurally-related Mn supertetrahedral T4 aggregates

Katerina Skordi, Antonis Anastassiades, Adeline D. Fournet, Rahul Kumar, Michael Schulze, Wolfgang Wernsdorfer, George Christou, Vassilios Nastopoulos, Spyros P. Perlepes, Constantina Papatriantafyllopoulou, Anastasios J. Tasiopoulos

Cellular & Molecular Medicine

Research output: Contribution to a Journal (Peer & Non Peer) › Article › peer-review

7 Citations (Scopus)

Abstract

The simultaneous employment of 1,3-propanediol and di-2-pyridyl ketone in Mn carboxylate chemistry has provided access to three new, structurally-related [Mn24] and [Mn23] clusters. They are based on nanosized supertetrahedal T4 Mn/O structural cores and exhibit slow relaxation of magnetization below 3.5 K.

Original language	English
Pages (from-to)	12484-12487
Number of pages	4
Journal	Chemical Communications
Volume	57
Issue number	93
DOIs	https://doi.org/10.1039/d1cc01815a
Publication status	Published - 4 Dec 2021

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title = "High nuclearity structurally-related Mn supertetrahedral T4 aggregates",

abstract = "The simultaneous employment of 1,3-propanediol and di-2-pyridyl ketone in Mn carboxylate chemistry has provided access to three new, structurally-related [Mn24] and [Mn23] clusters. They are based on nanosized supertetrahedal T4 Mn/O structural cores and exhibit slow relaxation of magnetization below 3.5 K.",

author = "Katerina Skordi and Antonis Anastassiades and Fournet, \{Adeline D.\} and Rahul Kumar and Michael Schulze and Wolfgang Wernsdorfer and George Christou and Vassilios Nastopoulos and Perlepes, \{Spyros P.\} and Constantina Papatriantafyllopoulou and Tasiopoulos, \{Anastasios J.\}",

note = "Publisher Copyright: {\textcopyright} The Royal Society of Chemistry.",

year = "2021",

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day = "4",

doi = "10.1039/d1cc01815a",

language = "English",

volume = "57",

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journal = "Chemical Communications",

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publisher = "Royal Society of Chemistry",

number = "93",

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TY - JOUR

T1 - High nuclearity structurally-related Mn supertetrahedral T4 aggregates

AU - Skordi, Katerina

AU - Anastassiades, Antonis

AU - Fournet, Adeline D.

AU - Kumar, Rahul

AU - Schulze, Michael

AU - Wernsdorfer, Wolfgang

AU - Christou, George

AU - Nastopoulos, Vassilios

AU - Perlepes, Spyros P.

AU - Papatriantafyllopoulou, Constantina

AU - Tasiopoulos, Anastasios J.

PY - 2021/12/4

Y1 - 2021/12/4

N2 - The simultaneous employment of 1,3-propanediol and di-2-pyridyl ketone in Mn carboxylate chemistry has provided access to three new, structurally-related [Mn24] and [Mn23] clusters. They are based on nanosized supertetrahedal T4 Mn/O structural cores and exhibit slow relaxation of magnetization below 3.5 K.

AB - The simultaneous employment of 1,3-propanediol and di-2-pyridyl ketone in Mn carboxylate chemistry has provided access to three new, structurally-related [Mn24] and [Mn23] clusters. They are based on nanosized supertetrahedal T4 Mn/O structural cores and exhibit slow relaxation of magnetization below 3.5 K.

UR - https://www.scopus.com/pages/publications/85120315469

U2 - 10.1039/d1cc01815a

DO - 10.1039/d1cc01815a

M3 - Article

SN - 1359-7345

VL - 57

SP - 12484

EP - 12487

JO - Chemical Communications

JF - Chemical Communications

IS - 93

ER -

High nuclearity structurally-related Mn supertetrahedral T4 aggregates

Abstract

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