Heteronuclear Pt-Pd, Pt2Cu and Pt2Ni complexes with bridging acetamidate: Crystal structures and spectroscopic studies

Andrea Erxleben; Alberto Albinati; Bernhard Lippert

doi:10.1039/DT9960001823

Heteronuclear Pt-Pd, Pt₂Cu and Pt₂Ni complexes with bridging acetamidate: Crystal structures and spectroscopic studies

Andrea Erxleben
, Alberto Albinati
, Bernhard Lippert

Research output: Contribution to a Journal (Peer & Non Peer) › Article › peer-review

20 Citations (Scopus)

Abstract

The reaction of trans- and cis-[Pt(NH₃)₂(NHCOMe-N)₂] 1 and 2 with heterometals [(en)Pd^II (en = ethane-1,2-diamine), Cu²⁺ or Ni²⁺] has been investigated. Dinuclear compounds of stoichiometry PtML₂ and trinuclear Pt₂ML₄ complexes with the heterometals co-ordinating through the amide oxygens have been characterised and studied in solution. The crystal structures of cis-[(NH₃)₂Pt(NHCOMe)₂Pd(en)][ClO ₄]_1.5[NO₃]_0.5 3, cis-[{Pt(NH₃)₂(NHCOMe)₂} ₂Cu][ClO₄]₂ 4 and cis-[{Pt(NH₃)₂(NHCOMe)₂} ₂Ni][ClO₄]₂ 5 have been determined.

Original language	English
Pages (from-to)	1823-1828
Number of pages	6
Journal	Journal of the Chemical Society, Dalton Transactions
Issue number	9
DOIs	https://doi.org/10.1039/DT9960001823
Publication status	Published - 7 May 1996
Externally published	Yes

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title = "Heteronuclear Pt-Pd, Pt2Cu and Pt2Ni complexes with bridging acetamidate: Crystal structures and spectroscopic studies",

abstract = "The reaction of trans- and cis-[Pt(NH3)2(NHCOMe-N)2] 1 and 2 with heterometals [(en)PdII (en = ethane-1,2-diamine), Cu2+ or Ni2+] has been investigated. Dinuclear compounds of stoichiometry PtML2 and trinuclear Pt2ML4 complexes with the heterometals co-ordinating through the amide oxygens have been characterised and studied in solution. The crystal structures of cis-[(NH3)2Pt(NHCOMe)2Pd(en)][ClO 4]1.5[NO3]0.5 3, cis-[\{Pt(NH3)2(NHCOMe)2\} 2Cu][ClO4]2 4 and cis-[\{Pt(NH3)2(NHCOMe)2\} 2Ni][ClO4]2 5 have been determined.",

author = "Andrea Erxleben and Alberto Albinati and Bernhard Lippert",

year = "1996",

month = may,

day = "7",

doi = "10.1039/DT9960001823",

language = "English",

pages = "1823--1828",

journal = "Journal of the Chemical Society, Dalton Transactions",

issn = "0300-9246",

publisher = "Royal Society of Chemistry",

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TY - JOUR

T1 - Heteronuclear Pt-Pd, Pt2Cu and Pt2Ni complexes with bridging acetamidate

T2 - Crystal structures and spectroscopic studies

AU - Erxleben, Andrea

AU - Albinati, Alberto

AU - Lippert, Bernhard

PY - 1996/5/7

Y1 - 1996/5/7

N2 - The reaction of trans- and cis-[Pt(NH3)2(NHCOMe-N)2] 1 and 2 with heterometals [(en)PdII (en = ethane-1,2-diamine), Cu2+ or Ni2+] has been investigated. Dinuclear compounds of stoichiometry PtML2 and trinuclear Pt2ML4 complexes with the heterometals co-ordinating through the amide oxygens have been characterised and studied in solution. The crystal structures of cis-[(NH3)2Pt(NHCOMe)2Pd(en)][ClO 4]1.5[NO3]0.5 3, cis-[{Pt(NH3)2(NHCOMe)2} 2Cu][ClO4]2 4 and cis-[{Pt(NH3)2(NHCOMe)2} 2Ni][ClO4]2 5 have been determined.

AB - The reaction of trans- and cis-[Pt(NH3)2(NHCOMe-N)2] 1 and 2 with heterometals [(en)PdII (en = ethane-1,2-diamine), Cu2+ or Ni2+] has been investigated. Dinuclear compounds of stoichiometry PtML2 and trinuclear Pt2ML4 complexes with the heterometals co-ordinating through the amide oxygens have been characterised and studied in solution. The crystal structures of cis-[(NH3)2Pt(NHCOMe)2Pd(en)][ClO 4]1.5[NO3]0.5 3, cis-[{Pt(NH3)2(NHCOMe)2} 2Cu][ClO4]2 4 and cis-[{Pt(NH3)2(NHCOMe)2} 2Ni][ClO4]2 5 have been determined.

UR - https://www.scopus.com/pages/publications/33748478116

U2 - 10.1039/DT9960001823

DO - 10.1039/DT9960001823

M3 - Article

SN - 0300-9246

SP - 1823

EP - 1828

JO - Journal of the Chemical Society, Dalton Transactions

JF - Journal of the Chemical Society, Dalton Transactions

IS - 9

ER -

Heteronuclear Pt-Pd, Pt₂Cu and Pt₂Ni complexes with bridging acetamidate: Crystal structures and spectroscopic studies

Abstract

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