First examples of polymeric mixed-metal (Pt-Ag) complexes containing single acetamidate bridges: cis-[(NH3)2Pt(NHCOMe)2Ag]NO 3·4H2O and trans-[(NH3)2Pt(NHCOMe)2Ag]NO 3·1.5H2O

Andrea Erxleben; Bernhard Lippert

doi:10.1039/dt9960002329

First examples of polymeric mixed-metal (Pt-Ag) complexes containing single acetamidate bridges: cis-[(NH₃)₂Pt(NHCOMe)₂Ag]NO ₃·4H₂O and trans-[(NH₃)₂Pt(NHCOMe)₂Ag]NO ₃·1.5H₂O

Andrea Erxleben
, Bernhard Lippert

Technische Universität Dortmund

Research output: Contribution to a Journal (Peer & Non Peer) › Article › peer-review

41 Citations (Scopus)

Abstract

The reaction of AgNO₃ with trans- and cis-[Pt(NH₃)₂(NHCOMe-N)₂] 1 and 2 yielded the heteronuclear polymeric complexes cis-[(NH₃)₂Pt(NHCOMe)₂Ag]NO ₃·4H₂O 3 and trans-[(NH₃)₂Pt(NHCOMe)₂Ag]NO ₃· 1.5H₂O 4. Complexes 3 and 4 have been studied in solution and characterised by X-ray analysis: 3, tetragonal, space group I4₁/a, a = b= 15.874(2), c = 22.918(5) Å, Z = 16; 4, triclinic, space group P1, a = 7.143(3), b = 8.416(5), c = 11.544(6) Å, α = 78.61(4), β = 89.67(4), γ = 83.79(4)°, Z = 2. The Pt ⋯ Ag distances are 2.897(1) and 2.903(1) (3) and 2.925(2) and 2.919(2) Å (4). Possible metal-metal bonding interactions are discussed.

Original language	English
Pages (from-to)	2329-2333
Number of pages	5
Journal	Journal of the Chemical Society, Dalton Transactions
Issue number	11
DOIs	https://doi.org/10.1039/dt9960002329
Publication status	Published - 7 Jun 1996
Externally published	Yes

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@article{576997c1dad74a4cb9988a4cfa3b390d,

title = "First examples of polymeric mixed-metal (Pt-Ag) complexes containing single acetamidate bridges: cis-[(NH3)2Pt(NHCOMe)2Ag]NO 3·4H2O and trans-[(NH3)2Pt(NHCOMe)2Ag]NO 3·1.5H2O",

abstract = "The reaction of AgNO3 with trans- and cis-[Pt(NH3)2(NHCOMe-N)2] 1 and 2 yielded the heteronuclear polymeric complexes cis-[(NH3)2Pt(NHCOMe)2Ag]NO 3·4H2O 3 and trans-[(NH3)2Pt(NHCOMe)2Ag]NO 3· 1.5H2O 4. Complexes 3 and 4 have been studied in solution and characterised by X-ray analysis: 3, tetragonal, space group I41/a, a = b= 15.874(2), c = 22.918(5) {\AA}, Z = 16; 4, triclinic, space group P1, a = 7.143(3), b = 8.416(5), c = 11.544(6) {\AA}, α = 78.61(4), β = 89.67(4), γ = 83.79(4)°, Z = 2. The Pt ⋯ Ag distances are 2.897(1) and 2.903(1) (3) and 2.925(2) and 2.919(2) {\AA} (4). Possible metal-metal bonding interactions are discussed.",

author = "Andrea Erxleben and Bernhard Lippert",

year = "1996",

month = jun,

day = "7",

doi = "10.1039/dt9960002329",

language = "English",

pages = "2329--2333",

journal = "Journal of the Chemical Society, Dalton Transactions",

issn = "0300-9246",

number = "11",

}

First examples of polymeric mixed-metal (Pt-Ag) complexes containing single acetamidate bridges: cis-[(NH₃)₂Pt(NHCOMe)₂Ag]NO ₃·4H₂O and trans-[(NH₃)₂Pt(NHCOMe)₂Ag]NO ₃·1.5H₂O. / Erxleben, Andrea; Lippert, Bernhard.
In: Journal of the Chemical Society, Dalton Transactions, No. 11, 07.06.1996, p. 2329-2333.

Research output: Contribution to a Journal (Peer & Non Peer) › Article › peer-review

TY - JOUR

T1 - First examples of polymeric mixed-metal (Pt-Ag) complexes containing single acetamidate bridges

T2 - cis-[(NH3)2Pt(NHCOMe)2Ag]NO 3·4H2O and trans-[(NH3)2Pt(NHCOMe)2Ag]NO 3·1.5H2O

AU - Erxleben, Andrea

AU - Lippert, Bernhard

PY - 1996/6/7

Y1 - 1996/6/7

N2 - The reaction of AgNO3 with trans- and cis-[Pt(NH3)2(NHCOMe-N)2] 1 and 2 yielded the heteronuclear polymeric complexes cis-[(NH3)2Pt(NHCOMe)2Ag]NO 3·4H2O 3 and trans-[(NH3)2Pt(NHCOMe)2Ag]NO 3· 1.5H2O 4. Complexes 3 and 4 have been studied in solution and characterised by X-ray analysis: 3, tetragonal, space group I41/a, a = b= 15.874(2), c = 22.918(5) Å, Z = 16; 4, triclinic, space group P1, a = 7.143(3), b = 8.416(5), c = 11.544(6) Å, α = 78.61(4), β = 89.67(4), γ = 83.79(4)°, Z = 2. The Pt ⋯ Ag distances are 2.897(1) and 2.903(1) (3) and 2.925(2) and 2.919(2) Å (4). Possible metal-metal bonding interactions are discussed.

AB - The reaction of AgNO3 with trans- and cis-[Pt(NH3)2(NHCOMe-N)2] 1 and 2 yielded the heteronuclear polymeric complexes cis-[(NH3)2Pt(NHCOMe)2Ag]NO 3·4H2O 3 and trans-[(NH3)2Pt(NHCOMe)2Ag]NO 3· 1.5H2O 4. Complexes 3 and 4 have been studied in solution and characterised by X-ray analysis: 3, tetragonal, space group I41/a, a = b= 15.874(2), c = 22.918(5) Å, Z = 16; 4, triclinic, space group P1, a = 7.143(3), b = 8.416(5), c = 11.544(6) Å, α = 78.61(4), β = 89.67(4), γ = 83.79(4)°, Z = 2. The Pt ⋯ Ag distances are 2.897(1) and 2.903(1) (3) and 2.925(2) and 2.919(2) Å (4). Possible metal-metal bonding interactions are discussed.

UR - https://www.scopus.com/pages/publications/33749307950

U2 - 10.1039/dt9960002329

DO - 10.1039/dt9960002329

M3 - Article

SN - 0300-9246

SP - 2329

EP - 2333

JO - Journal of the Chemical Society, Dalton Transactions

JF - Journal of the Chemical Society, Dalton Transactions

IS - 11

ER -

First examples of polymeric mixed-metal (Pt-Ag) complexes containing single acetamidate bridges: cis-[(NH₃)₂Pt(NHCOMe)₂Ag]NO ₃·4H₂O and trans-[(NH₃)₂Pt(NHCOMe)₂Ag]NO ₃·1.5H₂O

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