EXPERIMENTAL AND THEORETICAL-STUDIES OF CORRELATED ROTATION IN TRIS(ORTHO-TOLYL) DERIVATIVES OF P, ARSENIC AND SI

Patrick Mcardle

EXPERIMENTAL AND THEORETICAL-STUDIES OF CORRELATED ROTATION IN TRIS(ORTHO-TOLYL) DERIVATIVES OF P, ARSENIC AND SI

Patrick Mcardle

Cellular & Molecular Medicine

Research output: Contribution to a Journal (Peer & Non Peer) › Article › peer-review

Abstract

Variable temperature NMR studies have established equilibrium constants and or activation parameters for the exo2 exo3 equilibrium in the series M(o-tolyl)3 (M = P, As), XM (o-tolyl)3 (M = P, X = O, S, Se; M = As, X = O, S) and [MeM(o-tolyl)3]n+ (n = O, M = Si; n = 1, M = P, As). The crystal structure of OAs(o-tolyl)3H2O is reported. Molecular mechanics studies of P(o-tolyl)3, reproduce correctly the ground state exo3 conformation and provide an analysis of the lowest energy two-ring flip exchange mechanism.

Original language	English (Ireland)
Number of pages	7
Journal	Journal Of The Chemical Society-Perkin Transactions 2
Publication status	Published - 1 Oct 1992

Authors (Note for portal: view the doc link for the full list of authors)

Authors
HOWELL, JAS,PALIN, MG,YATES, PC,MCARDLE, P,CUNNINGHAM, D,GOLDSCHMIDT, Z,GOTTLIEB, HE,HEZRONILANGERMAN, D

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title = "EXPERIMENTAL AND THEORETICAL-STUDIES OF CORRELATED ROTATION IN TRIS(ORTHO-TOLYL) DERIVATIVES OF P, ARSENIC AND SI",

abstract = "Variable temperature NMR studies have established equilibrium constants and or activation parameters for the exo2 exo3 equilibrium in the series M(o-tolyl)3 (M = P, As), XM (o-tolyl)3 (M = P, X = O, S, Se; M = As, X = O, S) and [MeM(o-tolyl)3]n+ (n = O, M = Si; n = 1, M = P, As). The crystal structure of OAs(o-tolyl)3H2O is reported. Molecular mechanics studies of P(o-tolyl)3, reproduce correctly the ground state exo3 conformation and provide an analysis of the lowest energy two-ring flip exchange mechanism.",

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year = "1992",

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journal = "Journal Of The Chemical Society-Perkin Transactions 2",

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PY - 1992/10/1

Y1 - 1992/10/1

N2 - Variable temperature NMR studies have established equilibrium constants and or activation parameters for the exo2 exo3 equilibrium in the series M(o-tolyl)3 (M = P, As), XM (o-tolyl)3 (M = P, X = O, S, Se; M = As, X = O, S) and [MeM(o-tolyl)3]n+ (n = O, M = Si; n = 1, M = P, As). The crystal structure of OAs(o-tolyl)3H2O is reported. Molecular mechanics studies of P(o-tolyl)3, reproduce correctly the ground state exo3 conformation and provide an analysis of the lowest energy two-ring flip exchange mechanism.

AB - Variable temperature NMR studies have established equilibrium constants and or activation parameters for the exo2 exo3 equilibrium in the series M(o-tolyl)3 (M = P, As), XM (o-tolyl)3 (M = P, X = O, S, Se; M = As, X = O, S) and [MeM(o-tolyl)3]n+ (n = O, M = Si; n = 1, M = P, As). The crystal structure of OAs(o-tolyl)3H2O is reported. Molecular mechanics studies of P(o-tolyl)3, reproduce correctly the ground state exo3 conformation and provide an analysis of the lowest energy two-ring flip exchange mechanism.

M3 - Article

JO - Journal Of The Chemical Society-Perkin Transactions 2

JF - Journal Of The Chemical Society-Perkin Transactions 2

ER -

EXPERIMENTAL AND THEORETICAL-STUDIES OF CORRELATED ROTATION IN TRIS(ORTHO-TOLYL) DERIVATIVES OF P, ARSENIC AND SI

Abstract

Authors (Note for portal: view the doc link for the full list of authors)

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