EVIDENCE FOR CORRELATED ROTATION AND DIASTEREOISOMER DISCRIMINATION IN (ETA-4-DIENE)FE(CO)2L COMPLEXES - THE CRYSTAL AND SOLUTION STRUCTURES OF (CYCLOHEXADIENE)FE(CO)2P(ORTHO-TOLYL)3 AND (CYCLOHEPTADIENE)FE(CO)2(+)-PPH2(NEOMENTHYL)

Patrick Mcardle

EVIDENCE FOR CORRELATED ROTATION AND DIASTEREOISOMER DISCRIMINATION IN (ETA-4-DIENE)FE(CO)2L COMPLEXES - THE CRYSTAL AND SOLUTION STRUCTURES OF (CYCLOHEXADIENE)FE(CO)2P(ORTHO-TOLYL)3 AND (CYCLOHEPTADIENE)FE(CO)2(+)-PPH2(NEOMENTHYL)

Patrick Mcardle

Cellular & Molecular Medicine

Research output: Contribution to a Journal (Peer & Non Peer) › Article › peer-review

Abstract

The solid state structure of (cyclohexadiene)Fe(CO)2P(o-tolyl)3 reveals an exo2 conformation for the phosphine. In solution, arene ring exchange in the phosphine and exchange of phosphine between equivalent basal positions of the square pyramid occur at equal rates. In solution, (cycloheptadiene)Fe(CO)2(+)-PPh2(neomenthyl) exhibits a diastereoselection between basal isomers, and crystallizes as a single diastereoisomer which has been structurally characterized.

Original language	English (Ireland)
Number of pages	18
Journal	Journal Of Organometallic Chemistry
Volume	413
Publication status	Published - 1 Aug 1991

Authors (Note for portal: view the doc link for the full list of authors)

Authors
HOWELL, JAS,PALIN, MG,TIRVENGADUM, MC,CUNNINGHAM, D,MCARDLE, P,GOLDSCHMIDT, Z,GOTTLIEB, HE

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@article{14d13bdf0a0145878b9ae9145af63d3c,

title = "EVIDENCE FOR CORRELATED ROTATION AND DIASTEREOISOMER DISCRIMINATION IN (ETA-4-DIENE)FE(CO)2L COMPLEXES - THE CRYSTAL AND SOLUTION STRUCTURES OF (CYCLOHEXADIENE)FE(CO)2P(ORTHO-TOLYL)3 AND (CYCLOHEPTADIENE)FE(CO)2(+)-PPH2(NEOMENTHYL)",

abstract = "The solid state structure of (cyclohexadiene)Fe(CO)2P(o-tolyl)3 reveals an exo2 conformation for the phosphine. In solution, arene ring exchange in the phosphine and exchange of phosphine between equivalent basal positions of the square pyramid occur at equal rates. In solution, (cycloheptadiene)Fe(CO)2(+)-PPh2(neomenthyl) exhibits a diastereoselection between basal isomers, and crystallizes as a single diastereoisomer which has been structurally characterized.",

author = "Patrick Mcardle",

year = "1991",

month = aug,

day = "1",

language = "English (Ireland)",

volume = "413",

journal = "Journal Of Organometallic Chemistry",

}

EVIDENCE FOR CORRELATED ROTATION AND DIASTEREOISOMER DISCRIMINATION IN (ETA-4-DIENE)FE(CO)2L COMPLEXES - THE CRYSTAL AND SOLUTION STRUCTURES OF (CYCLOHEXADIENE)FE(CO)2P(ORTHO-TOLYL)3 AND (CYCLOHEPTADIENE)FE(CO)2(+)-PPH2(NEOMENTHYL). / Mcardle, Patrick.
In: Journal Of Organometallic Chemistry, Vol. 413, 01.08.1991.

Research output: Contribution to a Journal (Peer & Non Peer) › Article › peer-review

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T1 - EVIDENCE FOR CORRELATED ROTATION AND DIASTEREOISOMER DISCRIMINATION IN (ETA-4-DIENE)FE(CO)2L COMPLEXES - THE CRYSTAL AND SOLUTION STRUCTURES OF (CYCLOHEXADIENE)FE(CO)2P(ORTHO-TOLYL)3 AND (CYCLOHEPTADIENE)FE(CO)2(+)-PPH2(NEOMENTHYL)

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N2 - The solid state structure of (cyclohexadiene)Fe(CO)2P(o-tolyl)3 reveals an exo2 conformation for the phosphine. In solution, arene ring exchange in the phosphine and exchange of phosphine between equivalent basal positions of the square pyramid occur at equal rates. In solution, (cycloheptadiene)Fe(CO)2(+)-PPh2(neomenthyl) exhibits a diastereoselection between basal isomers, and crystallizes as a single diastereoisomer which has been structurally characterized.

AB - The solid state structure of (cyclohexadiene)Fe(CO)2P(o-tolyl)3 reveals an exo2 conformation for the phosphine. In solution, arene ring exchange in the phosphine and exchange of phosphine between equivalent basal positions of the square pyramid occur at equal rates. In solution, (cycloheptadiene)Fe(CO)2(+)-PPh2(neomenthyl) exhibits a diastereoselection between basal isomers, and crystallizes as a single diastereoisomer which has been structurally characterized.

M3 - Article

VL - 413

JO - Journal Of Organometallic Chemistry

JF - Journal Of Organometallic Chemistry

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