Abstract
We report the first enantioselective Rh-catalyzed Markovnikov hydroboration of unactivated terminal alkenes. Using a novel sp2-sp3 hybridized diboron reagent and water as a proton source, a broad range of alkenes undergo hydroboration to provide secondary boronic esters with high regio- and enantiocontrol.
| Original language | English (Ireland) |
|---|---|
| Pages (from-to) | 9148-9151 |
| Number of pages | 3 |
| Journal | Journal of the American Chemical Society |
| Volume | 139 |
| Issue number | 27 |
| DOIs | |
| Publication status | Published - 1 Jun 2017 |
Authors (Note for portal: view the doc link for the full list of authors)
- Authors
- James R. Smith and Beatrice S. L. Collins and Matthew J. Hesse and Mark A. Graham and Eddie L. Myers and Varinder K. Aggarwal
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