Discrete and encapsulated molecular grids: Homometallic Mn15 and heterometallic Mn24Ni2 aggregates

Maria Charalambous; Sotiris M. Zartilas; Eleni E. Moushi; Constantina Papatriantafyllopoulou; Manolis J. Manos; Theocharis C. Stamatatos; Shreya Mukherjee; Vassilios Nastopoulos; George Christou; Anastasios J. Tasiopoulos

doi:10.1039/c4cc02893g

Discrete and encapsulated molecular grids: Homometallic Mn₁₅ and heterometallic Mn₂₄Ni₂ aggregates

Maria Charalambous
, Sotiris M. Zartilas
, Eleni E. Moushi
, Constantina Papatriantafyllopoulou
, Manolis J. Manos
, Theocharis C. Stamatatos
, Shreya Mukherjee
, Vassilios Nastopoulos
, George Christou
, Anastasios J. Tasiopoulos

University of Cyprus
University of Florida
University of Patras

Research output: Contribution to a Journal (Peer & Non Peer) › Article › peer-review

11 Citations (Scopus)

Abstract

Two molecular grid-like clusters are reported, one is a discrete [3 × 5] grid and the other a [3 × 4] grid within a Mn₁₂Ni₂ loop. Both Mn₂₄Ni₂ and Mn₁₅ aggregates display novel and aesthetically pleasing structures with the former one being among the highest nuclearity heterometallic Mn_xM_y clusters (M = any transition metal ion).

Original language	English
Pages (from-to)	9090-9093
Number of pages	4
Journal	Chemical Communications
Volume	50
Issue number	65
DOIs	https://doi.org/10.1039/c4cc02893g
Publication status	Published - 17 Jul 2014
Externally published	Yes

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10.1039/c4cc02893g

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title = "Discrete and encapsulated molecular grids: Homometallic Mn15 and heterometallic Mn24Ni2 aggregates",

abstract = "Two molecular grid-like clusters are reported, one is a discrete [3 {\texttimes} 5] grid and the other a [3 {\texttimes} 4] grid within a Mn12Ni2 loop. Both Mn24Ni2 and Mn15 aggregates display novel and aesthetically pleasing structures with the former one being among the highest nuclearity heterometallic MnxMy clusters (M = any transition metal ion).",

author = "Maria Charalambous and Zartilas, \{Sotiris M.\} and Moushi, \{Eleni E.\} and Constantina Papatriantafyllopoulou and Manos, \{Manolis J.\} and Stamatatos, \{Theocharis C.\} and Shreya Mukherjee and Vassilios Nastopoulos and George Christou and Tasiopoulos, \{Anastasios J.\}",

year = "2014",

month = jul,

day = "17",

doi = "10.1039/c4cc02893g",

language = "English",

volume = "50",

pages = "9090--9093",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

number = "65",

}

TY - JOUR

T1 - Discrete and encapsulated molecular grids

T2 - Homometallic Mn15 and heterometallic Mn24Ni2 aggregates

AU - Charalambous, Maria

AU - Zartilas, Sotiris M.

AU - Moushi, Eleni E.

AU - Papatriantafyllopoulou, Constantina

AU - Manos, Manolis J.

AU - Stamatatos, Theocharis C.

AU - Mukherjee, Shreya

AU - Nastopoulos, Vassilios

AU - Christou, George

AU - Tasiopoulos, Anastasios J.

PY - 2014/7/17

Y1 - 2014/7/17

N2 - Two molecular grid-like clusters are reported, one is a discrete [3 × 5] grid and the other a [3 × 4] grid within a Mn12Ni2 loop. Both Mn24Ni2 and Mn15 aggregates display novel and aesthetically pleasing structures with the former one being among the highest nuclearity heterometallic MnxMy clusters (M = any transition metal ion).

AB - Two molecular grid-like clusters are reported, one is a discrete [3 × 5] grid and the other a [3 × 4] grid within a Mn12Ni2 loop. Both Mn24Ni2 and Mn15 aggregates display novel and aesthetically pleasing structures with the former one being among the highest nuclearity heterometallic MnxMy clusters (M = any transition metal ion).

UR - https://www.scopus.com/pages/publications/84904550383

U2 - 10.1039/c4cc02893g

DO - 10.1039/c4cc02893g

M3 - Article

SN - 1359-7345

VL - 50

SP - 9090

EP - 9093

JO - Chemical Communications

JF - Chemical Communications

IS - 65

ER -

Discrete and encapsulated molecular grids: Homometallic Mn₁₅ and heterometallic Mn₂₄Ni₂ aggregates

Abstract

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