Diastereoisomer separation and absolute configuration of (ortho- and (meta-MeC6H4CO2Me)Cr(CO)2L (L = (+)-neomenthyl-PPh2)

Gerard Jaouen; James A.S. Howell; Marie Claire Tirvengadum; Patrick McArdle; Desmond Cunningham

doi:10.1016/0022-328X(89)87274-2

Diastereoisomer separation and absolute configuration of (ortho- and (meta-MeC₆H₄CO₂Me)Cr(CO)₂L (L = (+)-neomenthyl-PPh₂)

Gerard Jaouen
, James A.S. Howell
, Marie Claire Tirvengadum
, Patrick McArdle
, Desmond Cunningham

Research output: Contribution to a Journal (Peer & Non Peer) › Article › peer-review

9 Citations (Scopus)

Abstract

Replacement of a carbonyl ligand by (+)-neomenthylPPh₂ provides a method for diastereoisomer separation of the methyl esters of (ortho- and (para-toluic acid)Cr(CO)₃. The absolute planar configuration have been assigned.

Original language	English
Pages (from-to)	51-64
Number of pages	14
Journal	Journal of Organometallic Chemistry
Volume	370
Issue number	1-3
DOIs	https://doi.org/10.1016/0022-328X(89)87274-2
Publication status	Published - 11 Jul 1989
Externally published	Yes

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10.1016/0022-328X(89)87274-2

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title = "Diastereoisomer separation and absolute configuration of (ortho- and (meta-MeC6H4CO2Me)Cr(CO)2L (L = (+)-neomenthyl-PPh2)",

abstract = "Replacement of a carbonyl ligand by (+)-neomenthylPPh2 provides a method for diastereoisomer separation of the methyl esters of (ortho- and (para-toluic acid)Cr(CO)3. The absolute planar configuration have been assigned.",

author = "Gerard Jaouen and Howell, \{James A.S.\} and Tirvengadum, \{Marie Claire\} and Patrick McArdle and Desmond Cunningham",

year = "1989",

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T1 - Diastereoisomer separation and absolute configuration of (ortho- and (meta-MeC6H4CO2Me)Cr(CO)2L (L = (+)-neomenthyl-PPh2)

AU - Jaouen, Gerard

AU - Howell, James A.S.

AU - Tirvengadum, Marie Claire

AU - McArdle, Patrick

AU - Cunningham, Desmond

PY - 1989/7/11

Y1 - 1989/7/11

N2 - Replacement of a carbonyl ligand by (+)-neomenthylPPh2 provides a method for diastereoisomer separation of the methyl esters of (ortho- and (para-toluic acid)Cr(CO)3. The absolute planar configuration have been assigned.

AB - Replacement of a carbonyl ligand by (+)-neomenthylPPh2 provides a method for diastereoisomer separation of the methyl esters of (ortho- and (para-toluic acid)Cr(CO)3. The absolute planar configuration have been assigned.

UR - https://www.scopus.com/pages/publications/0002540597

U2 - 10.1016/0022-328X(89)87274-2

DO - 10.1016/0022-328X(89)87274-2

M3 - Article

SN - 0022-328X

VL - 370

SP - 51

EP - 64

JO - Journal of Organometallic Chemistry

JF - Journal of Organometallic Chemistry

IS - 1-3

ER -

Diastereoisomer separation and absolute configuration of (ortho- and (meta-MeC₆H₄CO₂Me)Cr(CO)₂L (L = (+)-neomenthyl-PPh₂)

Abstract

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