TY - GEN
T1 - COMPLEXATION OF COBALT(II) BY THE HYDROGENATED FORM OF N,N-O-PHENYLENEBIS(SALICYLIDENEIMINE) - THE CRYSTAL-STRUCTURE OF A TRINUCLEAR COBALT(II) COMPLEX
AU - Mcardle, Patrick
PY - 1991/11/1
Y1 - 1991/11/1
N2 - The reaction of N,N-o-phenylenebis(salicylideneimine), H2salphen, with sodium sand led to the hydrogenation of both imino groups of the ligand for 1 3 of the amount of H2salphen present. By adding CoCl2.1.5thf (thf = tetrahydrofuran) to the ligand mixture a trinuclear cobalt(II) complex 1 was isolated, and its structure determined. Crystallographic details: space group C2 c (monoclinic), a = 37.070(5), b = 14.036(2), c = 32.754(4) angstrom, beta = 102.07 (2)-degrees, Z = 12 trimeric molecules, and R = 0.084 (R = 0.095) for 7332 independent observed reflections with I 3-sigma(I).
AB - The reaction of N,N-o-phenylenebis(salicylideneimine), H2salphen, with sodium sand led to the hydrogenation of both imino groups of the ligand for 1 3 of the amount of H2salphen present. By adding CoCl2.1.5thf (thf = tetrahydrofuran) to the ligand mixture a trinuclear cobalt(II) complex 1 was isolated, and its structure determined. Crystallographic details: space group C2 c (monoclinic), a = 37.070(5), b = 14.036(2), c = 32.754(4) angstrom, beta = 102.07 (2)-degrees, Z = 12 trimeric molecules, and R = 0.084 (R = 0.095) for 7332 independent observed reflections with I 3-sigma(I).
M3 - Other contribution
ER -