Biocatalytic anode for glucose oxidation utilizing carbon nanotubes for direct electron transfer with glucose oxidase

Abhay Vaze; Nighat Hussain; Chi Tang; Donal Leech; James Rusling

doi:10.1016/j.elecom.2009.08.039

Biocatalytic anode for glucose oxidation utilizing carbon nanotubes for direct electron transfer with glucose oxidase

Abhay Vaze, Nighat Hussain, Chi Tang, Donal Leech, James Rusling

Cellular & Molecular Medicine

Research output: Contribution to a Journal (Peer & Non Peer) › Article › peer-review

53 Citations (Scopus)

Abstract

Covalently linked layers of glucose oxidase, single-wall carbon nanotubes and poly-l-lysine on pyrolytic graphite resulted in a stable biofuel cell anode featuring direct electron transfer from the enzyme. Catalytic response observed upon addition of glucose was due to electrochemical oxidation of FADH₂ under aerobic conditions. The electrode potential depended on glucose concentration. This system has essential attributes of an anode in a mediator-free biocatalytic fuel cell.

Original language	English
Pages (from-to)	2004-2007
Number of pages	4
Journal	Electrochemistry Communications
Volume	11
Issue number	10
DOIs	https://doi.org/10.1016/j.elecom.2009.08.039
Publication status	Published - Oct 2009

Keywords

Anode stability
Biofuel cell
Carbon nanotubes
Direct electron transfer
Glucose oxidase

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

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10.1016/j.elecom.2009.08.039

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title = "Biocatalytic anode for glucose oxidation utilizing carbon nanotubes for direct electron transfer with glucose oxidase",

abstract = "Covalently linked layers of glucose oxidase, single-wall carbon nanotubes and poly-l-lysine on pyrolytic graphite resulted in a stable biofuel cell anode featuring direct electron transfer from the enzyme. Catalytic response observed upon addition of glucose was due to electrochemical oxidation of FADH2 under aerobic conditions. The electrode potential depended on glucose concentration. This system has essential attributes of an anode in a mediator-free biocatalytic fuel cell.",

keywords = "Anode stability, Biofuel cell, Carbon nanotubes, Direct electron transfer, Glucose oxidase",

author = "Abhay Vaze and Nighat Hussain and Chi Tang and Donal Leech and James Rusling",

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T1 - Biocatalytic anode for glucose oxidation utilizing carbon nanotubes for direct electron transfer with glucose oxidase

AU - Vaze, Abhay

AU - Hussain, Nighat

AU - Tang, Chi

AU - Leech, Donal

AU - Rusling, James

PY - 2009/10

Y1 - 2009/10

N2 - Covalently linked layers of glucose oxidase, single-wall carbon nanotubes and poly-l-lysine on pyrolytic graphite resulted in a stable biofuel cell anode featuring direct electron transfer from the enzyme. Catalytic response observed upon addition of glucose was due to electrochemical oxidation of FADH2 under aerobic conditions. The electrode potential depended on glucose concentration. This system has essential attributes of an anode in a mediator-free biocatalytic fuel cell.

AB - Covalently linked layers of glucose oxidase, single-wall carbon nanotubes and poly-l-lysine on pyrolytic graphite resulted in a stable biofuel cell anode featuring direct electron transfer from the enzyme. Catalytic response observed upon addition of glucose was due to electrochemical oxidation of FADH2 under aerobic conditions. The electrode potential depended on glucose concentration. This system has essential attributes of an anode in a mediator-free biocatalytic fuel cell.

KW - Anode stability

KW - Biofuel cell

KW - Carbon nanotubes

KW - Direct electron transfer

KW - Glucose oxidase

UR - https://www.scopus.com/pages/publications/70349734865

U2 - 10.1016/j.elecom.2009.08.039

DO - 10.1016/j.elecom.2009.08.039

M3 - Article

SN - 1388-2481

VL - 11

SP - 2004

EP - 2007

JO - Electrochemistry Communications

JF - Electrochemistry Communications

IS - 10

ER -

Biocatalytic anode for glucose oxidation utilizing carbon nanotubes for direct electron transfer with glucose oxidase

Abstract

Keywords

UN SDGs

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