@inproceedings{8e7e533db6ee4ecf9661b824f27b57f0,
title = "Autoignition behavior of unsaturated hydrocarbons in the low and high temperature regions",
abstract = "In this work, numerical and experimental techniques are used to investigate the effect of the position of the double bond on the ignition properties of pentene and hexene linear isomers. A wide-range kinetic model for the oxidation of C5-C6 linear alkenes has been developed. Literature rapid compression machine data were used to validate the model at low temperatures and new shock tube experiments were performed in order to assess the behavior of the considered alkenes in the high temperature region. Some interesting inversions in the relative reactivity of the isomers were detected. The model successfully reproduced the measured behavior and allowed to explain the reason of these reactivity changes. The information gathered will be applied to the development of the kinetic mechanisms of larger unsaturated surrogate components.",
author = "Marco Mehl and Pitz, {William J.} and Westbrook, {Charles K.} and Kenji Yasunaga and Curran, {Henry J.}",
year = "2010",
language = "English",
series = "Western States Section of the Combustion Institute Spring Technical Meeting 2010",
publisher = "Western States Section/Combustion Institute",
pages = "817--849",
booktitle = "Western States Section of the Combustion Institute Spring Technical Meeting 2010",
note = "Western States Section of the Combustion Institute Spring Technical Meeting 2010 ; Conference date: 22-03-2010 Through 23-03-2010",
}