Assessment of the long-term leaching characteristics of cement-slag stabilized/solidified contaminated sediment

The use of stabilized/solidified (S/S) soils and sediments as sustainable construction materials is a global concern due to the potential risk of contaminant leaching including potentially toxic elements. The long-term leachability of four metals (Zn, Pb, Cd and As) in sediments mixed with OPC (Ordinary Portland Cement) and OPC/GGBS (Ground Granulated Blast Furnace Slag) binders were investigated through a combination of tank leaching tests and kinetic leaching models, with varying ranges of curing ages and ambient pH. The leaching data revealed that both binder compositions offer an excellent immobilization capacity for the four metals, while their releases are strongly pH-dependent and are a complex function of curing time. The partial replacement of OPC by GGBS is more effective for fixing Zn and As at pH of 1, Pb at pH of 7, Zn and Pb at pH of 10. Controlling leaching mechanisms and leachability indices were determined using nonlinear regression analysis and kinetic leaching models. The first-order diffusion model (FRDM) was the most applicable model for describing the leaching characteristics of these metals under the investigated cases, the leaching rate is controlled by surface wash-off initially and then by diffusion. The leachability indices indicate that the cement-slag S/S sediment can be regarded as an environmentally sustainable material with potential beneficial uses in construction.