TY - JOUR
T1 - An investigation of the thermal decomposition of the methohydroxides and methodeuterio-oxides of some 5-N,N-dimethylaminopent-1-enes
AU - Cocker, Wesley
AU - Geraghty, Niall W.A.
AU - McMurry, T. Brian H.
AU - Shannon, Patrick V.R.
PY - 1984
Y1 - 1984
N2 - The base-catalysed thermal decomposition of a number of quaternary bases of the type (R1)2C=CHC(R2)2C(R 3)2CH2N+Me3X- (R1 = H, Me; R2 = H, 2H; R3 = H, 2H, Me; X = OH,O2H) has been investigated. It is shown that the reaction is initiated by attack of base (OH, Ō2H, ylide) on an allylic proton or [2H]. A mechanism for the reaction is suggested.
AB - The base-catalysed thermal decomposition of a number of quaternary bases of the type (R1)2C=CHC(R2)2C(R 3)2CH2N+Me3X- (R1 = H, Me; R2 = H, 2H; R3 = H, 2H, Me; X = OH,O2H) has been investigated. It is shown that the reaction is initiated by attack of base (OH, Ō2H, ylide) on an allylic proton or [2H]. A mechanism for the reaction is suggested.
UR - http://www.scopus.com/inward/record.url?scp=37049113010&partnerID=8YFLogxK
U2 - 10.1039/p19840002245
DO - 10.1039/p19840002245
M3 - Article
SN - 1472-7781
SP - 2245
EP - 2254
JO - Journal of the Chemical Society - Perkin Transactions 1
JF - Journal of the Chemical Society - Perkin Transactions 1
ER -