An investigation of the accelerated thermal degradation of different epoxy resin composites using X-ray microcomputed tomography and optical coherence tomography

Epoxy resin composites reinforced with hollow glass microspheres, microlight microspheres, 3D parabeam glass, and E-Glass individually were subjected to accelerated thermal degradation conditions. X-ray microcomputed tomography (Xμ CT) was used to evaluate density changes, reinforcement filler damage, homogeneity, cracks and microcracks in the bulk of the different epoxy resin composites. Xμ CT 3D images, 2D reconstructed images and voids calculations revealed microspheres damage, filler distributions and showed cracks in all composites with different shapes and volume in response to the thermal degradation conditions. In addition, expansion of air bubbles/voids was observed and recorded in the microsphere and microlight epoxy composite samples. In a complementary way, optical coherence tomography (OCT) was used as a novel optical characterization technique to study structural changes of the surface and near-surface regions of the composites, uncovering signs of surface shrinkage caused by the thermal treatment. Thus, combining Xμ CT and OCT proved useful in examining epoxy resin composites' structure, filler-resin interface and surface characteristics.