A single-chain magnet based on linear [MnIII2MnII] units

Constantina Papatriantafyllopoulou; Sotiris Zartilas; Manolis J. Manos; Céline Pichon; Rodolphe Clérac; Anastasios J. Tasiopoulos

doi:10.1039/c4cc05687f

A single-chain magnet based on linear [Mn^III₂Mn^II] units

Constantina Papatriantafyllopoulou
, Sotiris Zartilas
, Manolis J. Manos
, Céline Pichon
, Rodolphe Clérac
, Anastasios J. Tasiopoulos

University of Cyprus
University of Ioannina
Unité Propre de Recherche
University Bordeaux-Segalen

Research output: Contribution to a Journal (Peer & Non Peer) › Article › peer-review

25 Citations (Scopus)

Abstract

The synthesis, structural characterization and magnetic properties of a 1D coordination polymer based on a linear mixed valent [Mn^III₂Mn^II] repeating unit are described. It displays single-chain magnet (SCM) behaviour with an energy barrier of ∼38 K and represents the first example of a mixed valent Mn–carboxylate SCM with a linear architecture.

Original language	English
Pages (from-to)	14873-14876
Number of pages	4
Journal	Chemical Communications
Volume	50
Issue number	94
DOIs	https://doi.org/10.1039/c4cc05687f
Publication status	Published - 30 Oct 2014
Externally published	Yes

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10.1039/c4cc05687f

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title = "A single-chain magnet based on linear [MnIII2MnII] units",

abstract = "The synthesis, structural characterization and magnetic properties of a 1D coordination polymer based on a linear mixed valent [MnIII2MnII] repeating unit are described. It displays single-chain magnet (SCM) behaviour with an energy barrier of ∼38 K and represents the first example of a mixed valent Mn{\textendash}carboxylate SCM with a linear architecture.",

author = "Constantina Papatriantafyllopoulou and Sotiris Zartilas and Manos, \{Manolis J.\} and C{\'e}line Pichon and Rodolphe Cl{\'e}rac and Tasiopoulos, \{Anastasios J.\}",

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doi = "10.1039/c4cc05687f",

language = "English",

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T1 - A single-chain magnet based on linear [MnIII2MnII] units

AU - Papatriantafyllopoulou, Constantina

AU - Zartilas, Sotiris

AU - Manos, Manolis J.

AU - Pichon, Céline

AU - Clérac, Rodolphe

AU - Tasiopoulos, Anastasios J.

PY - 2014/10/30

Y1 - 2014/10/30

N2 - The synthesis, structural characterization and magnetic properties of a 1D coordination polymer based on a linear mixed valent [MnIII2MnII] repeating unit are described. It displays single-chain magnet (SCM) behaviour with an energy barrier of ∼38 K and represents the first example of a mixed valent Mn–carboxylate SCM with a linear architecture.

AB - The synthesis, structural characterization and magnetic properties of a 1D coordination polymer based on a linear mixed valent [MnIII2MnII] repeating unit are described. It displays single-chain magnet (SCM) behaviour with an energy barrier of ∼38 K and represents the first example of a mixed valent Mn–carboxylate SCM with a linear architecture.

UR - https://www.scopus.com/pages/publications/84908621941

U2 - 10.1039/c4cc05687f

DO - 10.1039/c4cc05687f

M3 - Article

SN - 1359-7345

VL - 50

SP - 14873

EP - 14876

JO - Chemical Communications

JF - Chemical Communications

IS - 94

ER -

A single-chain magnet based on linear [Mn^III₂Mn^II] units

Abstract

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