A Phosphine-mediated conversion of azides into diazo compounds

Eddie L. Myers; Ronald T. Raines

doi:10.1002/anie.200804689

A Phosphine-mediated conversion of azides into diazo compounds

Eddie L. Myers
, Ronald T. Raines

University of Wisconsin-Madison

Research output: Contribution to a Journal (Peer & Non Peer) › Article › peer-review

90 Citations (Scopus)

Abstract

N2 the mild: Diazo compounds are extremely versatile intermediates for synthetic organic chemistry, but their synthesis can be challenging in the presence of delicate functional groups. The Staudinger ligation has inspired a mild method for the conversion of a broad range of azides into their diazo compound derivatives through an acyl triazene intermediate.

Original language	English
Pages (from-to)	2359-2363
Number of pages	5
Journal	Angewandte Chemie - International Edition
Volume	48
Issue number	13
DOIs	https://doi.org/10.1002/anie.200804689
Publication status	Published - 16 Mar 2009
Externally published	Yes

Keywords

Azides
Heterocycles
Phosphines
Staudinger reactionm
Synthetic methods

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10.1002/anie.200804689

Cite this

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title = "A Phosphine-mediated conversion of azides into diazo compounds",

abstract = "N2 the mild: Diazo compounds are extremely versatile intermediates for synthetic organic chemistry, but their synthesis can be challenging in the presence of delicate functional groups. The Staudinger ligation has inspired a mild method for the conversion of a broad range of azides into their diazo compound derivatives through an acyl triazene intermediate.",

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AU - Raines, Ronald T.

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AB - N2 the mild: Diazo compounds are extremely versatile intermediates for synthetic organic chemistry, but their synthesis can be challenging in the presence of delicate functional groups. The Staudinger ligation has inspired a mild method for the conversion of a broad range of azides into their diazo compound derivatives through an acyl triazene intermediate.

KW - Azides

KW - Heterocycles

KW - Phosphines

KW - Staudinger reactionm

KW - Synthetic methods

UR - https://www.scopus.com/pages/publications/70349786390

U2 - 10.1002/anie.200804689

DO - 10.1002/anie.200804689

M3 - Article

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JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

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ER -

A Phosphine-mediated conversion of azides into diazo compounds

Abstract

Keywords

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