A Mn36Ni4loop-of-loops-and-supertetrahedra’ aggregate possessing a high ST = 26 ± 1 spin ground state

Maria Charalambous; Eleni E. Moushi; Constantina Papatriantafyllopoulou; Wolfgang Wernsdorfer; Vassilios Nastopoulos; George Christou; Anastasios J. Tasiopoulos

doi:10.1039/c2cc30654a

A Mn₃₆Ni₄loop-of-loops-and-supertetrahedra’ aggregate possessing a high S_T = 26 ± 1 spin ground state

Maria Charalambous, Eleni E. Moushi, Constantina Papatriantafyllopoulou, Wolfgang Wernsdorfer, Vassilios Nastopoulos, George Christou, Anastasios J. Tasiopoulos

Research output: Contribution to a Journal (Peer & Non Peer) › Article › peer-review

39 Citations (Scopus)

Abstract

The initial use of 1,3-propanediol in mixed Mn/3d cluster chemistry has led to a Mn^III₂₈Mn^II₈Ni^II₄ molecular aggregate which consists of two Mn^III₈Ni₂ loops and two Mn^III₆Mn^II₄ supertetrahedral units and displays a high ground spin state value S_T = 26 ± 1.

Original language	English
Pages (from-to)	5410-5412
Number of pages	3
Journal	Chemical Communications
Volume	48
Issue number	44
DOIs	https://doi.org/10.1039/c2cc30654a
Publication status	Published - 7 May 2012
Externally published	Yes

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title = "A Mn36Ni4loop-of-loops-and-supertetrahedra{\textquoteright} aggregate possessing a high ST = 26 ± 1 spin ground state",

abstract = "The initial use of 1,3-propanediol in mixed Mn/3d cluster chemistry has led to a MnIII28MnII8NiII4 molecular aggregate which consists of two MnIII8Ni2 loops and two MnIII6MnII4 supertetrahedral units and displays a high ground spin state value ST = 26 ± 1.",

author = "Maria Charalambous and Moushi, \{Eleni E.\} and Constantina Papatriantafyllopoulou and Wolfgang Wernsdorfer and Vassilios Nastopoulos and George Christou and Tasiopoulos, \{Anastasios J.\}",

year = "2012",

month = may,

day = "7",

doi = "10.1039/c2cc30654a",

language = "English",

volume = "48",

pages = "5410--5412",

journal = "Chemical Communications",

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publisher = "Royal Society of Chemistry",

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T1 - A Mn36Ni4loop-of-loops-and-supertetrahedra’ aggregate possessing a high ST = 26 ± 1 spin ground state

AU - Charalambous, Maria

AU - Moushi, Eleni E.

AU - Papatriantafyllopoulou, Constantina

AU - Wernsdorfer, Wolfgang

AU - Nastopoulos, Vassilios

AU - Christou, George

AU - Tasiopoulos, Anastasios J.

PY - 2012/5/7

Y1 - 2012/5/7

N2 - The initial use of 1,3-propanediol in mixed Mn/3d cluster chemistry has led to a MnIII28MnII8NiII4 molecular aggregate which consists of two MnIII8Ni2 loops and two MnIII6MnII4 supertetrahedral units and displays a high ground spin state value ST = 26 ± 1.

AB - The initial use of 1,3-propanediol in mixed Mn/3d cluster chemistry has led to a MnIII28MnII8NiII4 molecular aggregate which consists of two MnIII8Ni2 loops and two MnIII6MnII4 supertetrahedral units and displays a high ground spin state value ST = 26 ± 1.

UR - https://www.scopus.com/pages/publications/84861595851

U2 - 10.1039/c2cc30654a

DO - 10.1039/c2cc30654a

M3 - Article

SN - 1359-7345

VL - 48

SP - 5410

EP - 5412

JO - Chemical Communications

JF - Chemical Communications

IS - 44

ER -

A Mn₃₆Ni₄loop-of-loops-and-supertetrahedra’ aggregate possessing a high S_T = 26 ± 1 spin ground state

Abstract

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