A high-nuclearity 3d/4f metal oxime cluster: An unusual Ni 8Dy8 "core-Shell" complex from the use of 2-pyridinealdoxime

Constantina Papatriantafyllopoulou; Theocharis C. Stamatatos; Constantinos G. Efthymiou; Luis Cunha-Silva; Filipe A.Almeida Paz; Spyros P. Perlepes; George Christou

doi:10.1021/ic101581g

A high-nuclearity 3d/4f metal oxime cluster: An unusual Ni ₈Dy₈ "core-Shell" complex from the use of 2-pyridinealdoxime

Constantina Papatriantafyllopoulou
, Theocharis C. Stamatatos
, Constantinos G. Efthymiou
, Luis Cunha-Silva
, Filipe A.Almeida Paz
, Spyros P. Perlepes
, George Christou

University of Florida
University of Patras
University of Porto
Instituto Superior Técnico
University of Aveiro

Research output: Contribution to a Journal (Peer & Non Peer) › Article › peer-review

93 Citations (Scopus)

Abstract

The initial employment of 2-pyridinealdoxime in 3d/4f chemistry has led to a Ni^II₈Dy^III₈ cluster with an unprecedented metal topology; the compound has an unusual structure, is the highest-nuclearity metal oxime cluster to date, and exhibits slow magnetization relaxation.

Original language	English
Pages (from-to)	9743-9745
Number of pages	3
Journal	Inorganic Chemistry
Volume	49
Issue number	21
DOIs	https://doi.org/10.1021/ic101581g
Publication status	Published - 1 Nov 2010
Externally published	Yes

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10.1021/ic101581g

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title = "A high-nuclearity 3d/4f metal oxime cluster: An unusual Ni 8Dy8 {"}core-Shell{"} complex from the use of 2-pyridinealdoxime",

abstract = "The initial employment of 2-pyridinealdoxime in 3d/4f chemistry has led to a NiII8DyIII8 cluster with an unprecedented metal topology; the compound has an unusual structure, is the highest-nuclearity metal oxime cluster to date, and exhibits slow magnetization relaxation.",

author = "Constantina Papatriantafyllopoulou and Stamatatos, \{Theocharis C.\} and Efthymiou, \{Constantinos G.\} and Luis Cunha-Silva and Paz, \{Filipe A.Almeida\} and Perlepes, \{Spyros P.\} and George Christou",

year = "2010",

month = nov,

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doi = "10.1021/ic101581g",

language = "English",

volume = "49",

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journal = "Inorganic Chemistry",

issn = "0020-1669",

publisher = "American Chemical Society",

number = "21",

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A high-nuclearity 3d/4f metal oxime cluster: An unusual Ni ₈Dy₈ "core-Shell" complex from the use of 2-pyridinealdoxime. / Papatriantafyllopoulou, Constantina; Stamatatos, Theocharis C.; Efthymiou, Constantinos G. et al.
In: Inorganic Chemistry, Vol. 49, No. 21, 01.11.2010, p. 9743-9745.

Research output: Contribution to a Journal (Peer & Non Peer) › Article › peer-review

TY - JOUR

T1 - A high-nuclearity 3d/4f metal oxime cluster

T2 - An unusual Ni 8Dy8 "core-Shell" complex from the use of 2-pyridinealdoxime

AU - Papatriantafyllopoulou, Constantina

AU - Stamatatos, Theocharis C.

AU - Efthymiou, Constantinos G.

AU - Cunha-Silva, Luis

AU - Paz, Filipe A.Almeida

AU - Perlepes, Spyros P.

AU - Christou, George

PY - 2010/11/1

Y1 - 2010/11/1

N2 - The initial employment of 2-pyridinealdoxime in 3d/4f chemistry has led to a NiII8DyIII8 cluster with an unprecedented metal topology; the compound has an unusual structure, is the highest-nuclearity metal oxime cluster to date, and exhibits slow magnetization relaxation.

AB - The initial employment of 2-pyridinealdoxime in 3d/4f chemistry has led to a NiII8DyIII8 cluster with an unprecedented metal topology; the compound has an unusual structure, is the highest-nuclearity metal oxime cluster to date, and exhibits slow magnetization relaxation.

UR - https://www.scopus.com/pages/publications/78049291911

U2 - 10.1021/ic101581g

DO - 10.1021/ic101581g

M3 - Article

SN - 0020-1669

VL - 49

SP - 9743

EP - 9745

JO - Inorganic Chemistry

JF - Inorganic Chemistry

IS - 21

ER -

A high-nuclearity 3d/4f metal oxime cluster: An unusual Ni ₈Dy₈ "core-Shell" complex from the use of 2-pyridinealdoxime

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