1,2,3,5-Tetrazines and 1,2,3-triazaspiro[4.4]nonanes: Remarkable products from 1,3-dipolar cycloadditions of N-sulphinylamines with substituted triazolium imides

Richard N. Butler; D. Cunningham; Patrick McArdle; Gerard A. O'Halloran

doi:10.1039/C39880000232

1,2,3,5-Tetrazines and 1,2,3-triazaspiro[4.4]nonanes: Remarkable products from 1,3-dipolar cycloadditions of N-sulphinylamines with substituted triazolium imides

Richard N. Butler
, D. Cunningham
, Patrick McArdle
, Gerard A. O'Halloran

University of Galway

Research output: Contribution to a Journal (Peer & Non Peer) › Article › peer-review

14 Citations (Scopus)

Abstract

Cycloadditions of aryl-N-sulphinylamines with substituted triazolium imides gave new 8π-2,4,5,6-tetrasubstituted-1,2,3,5-tetrazines, the X-ray crystal structure 〈′Uone of which is reported; strained tricyclic tetra-aza tetracyclo[4.3.1.0^1,6]decenes are suspected as intermediates and attempts to intercept them led to new substituted 1,2,3-triazaspiro[4.4]nonanes, the X-ray crystal structure of one of which is reported.

Original language	English
Pages (from-to)	232-234
Number of pages	3
Journal	Journal of the Chemical Society D: Chemical Communications
Issue number	3
DOIs	https://doi.org/10.1039/C39880000232
Publication status	Published - 1988
Externally published	Yes

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10.1039/C39880000232

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@article{f9789fa39819401ba0c6627fce227495,

title = "1,2,3,5-Tetrazines and 1,2,3-triazaspiro[4.4]nonanes: Remarkable products from 1,3-dipolar cycloadditions of N-sulphinylamines with substituted triazolium imides",

abstract = "Cycloadditions of aryl-N-sulphinylamines with substituted triazolium imides gave new 8π-2,4,5,6-tetrasubstituted-1,2,3,5-tetrazines, the X-ray crystal structure 〈′Uone of which is reported; strained tricyclic tetra-aza tetracyclo[4.3.1.01,6]decenes are suspected as intermediates and attempts to intercept them led to new substituted 1,2,3-triazaspiro[4.4]nonanes, the X-ray crystal structure of one of which is reported.",

author = "Butler, \{Richard N.\} and D. Cunningham and Patrick McArdle and O'Halloran, \{Gerard A.\}",

year = "1988",

doi = "10.1039/C39880000232",

language = "English",

pages = "232--234",

journal = "Journal of the Chemical Society D: Chemical Communications",

issn = "0022-4936",

publisher = "Chemical Society",

number = "3",

}

1,2,3,5-Tetrazines and 1,2,3-triazaspiro[4.4]nonanes: Remarkable products from 1,3-dipolar cycloadditions of N-sulphinylamines with substituted triazolium imides. / Butler, Richard N.; Cunningham, D.; McArdle, Patrick et al.
In: Journal of the Chemical Society D: Chemical Communications, No. 3, 1988, p. 232-234.

Research output: Contribution to a Journal (Peer & Non Peer) › Article › peer-review

TY - JOUR

T1 - 1,2,3,5-Tetrazines and 1,2,3-triazaspiro[4.4]nonanes

T2 - Remarkable products from 1,3-dipolar cycloadditions of N-sulphinylamines with substituted triazolium imides

AU - Butler, Richard N.

AU - Cunningham, D.

AU - McArdle, Patrick

AU - O'Halloran, Gerard A.

PY - 1988

Y1 - 1988

N2 - Cycloadditions of aryl-N-sulphinylamines with substituted triazolium imides gave new 8π-2,4,5,6-tetrasubstituted-1,2,3,5-tetrazines, the X-ray crystal structure 〈′Uone of which is reported; strained tricyclic tetra-aza tetracyclo[4.3.1.01,6]decenes are suspected as intermediates and attempts to intercept them led to new substituted 1,2,3-triazaspiro[4.4]nonanes, the X-ray crystal structure of one of which is reported.

AB - Cycloadditions of aryl-N-sulphinylamines with substituted triazolium imides gave new 8π-2,4,5,6-tetrasubstituted-1,2,3,5-tetrazines, the X-ray crystal structure 〈′Uone of which is reported; strained tricyclic tetra-aza tetracyclo[4.3.1.01,6]decenes are suspected as intermediates and attempts to intercept them led to new substituted 1,2,3-triazaspiro[4.4]nonanes, the X-ray crystal structure of one of which is reported.

UR - https://www.scopus.com/pages/publications/37049075535

U2 - 10.1039/C39880000232

DO - 10.1039/C39880000232

M3 - Article

SN - 0022-4936

SP - 232

EP - 234

JO - Journal of the Chemical Society D: Chemical Communications

JF - Journal of the Chemical Society D: Chemical Communications

IS - 3

ER -

1,2,3,5-Tetrazines and 1,2,3-triazaspiro[4.4]nonanes: Remarkable products from 1,3-dipolar cycloadditions of N-sulphinylamines with substituted triazolium imides

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